氖的极化率和磁化率的理论测定

M. Lesiuk, M. Przybytek, B. Jeziorski
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引用次数: 8

摘要

我们报告了氖原子偶极极化率的理论测定,包括其频率依赖性。考虑了相对论、量子电动力学、有限核质量和有限核尺寸效应的修正。静态极化率为$\alpha_0=2.66080(36)$,前两个极化率色散系数(柯西矩)为$\alpha_2=2.850(7)$和$\alpha_4=4.932(14)$;所有值都以原子单位(a.u)表示。在静态极化率的情况下,我们的结果与最佳实验测定结果一致[C]。盖瑟和B.费莫斯,物理学家。Rev. Lett. 120, 123203(2018)],但我们估计的不确定性要大得多。对于色散系数,与已发表的理论和实验数据相比,这项工作获得的结果似乎是迄今为止最准确的。我们还计算了氖原子的静态磁化率,得到了气态氖的折射率。我们的结果,$\chi_0 = -8.484(19) \cdot 10^{-5}$ a.u,大约是9% larger in absolute value than the recommended experimental value [CRC Handbook of Chemistry and Physics, CRC Press, 2019, p. 4-145].
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Theoretical determination of polarizability and magnetic susceptibility of neon
We report theoretical determination of the dipole polarizability of the neon atom, including its frequency dependence. Corrections for the relativistic, quantum electrodynamics, finite nuclear mass, and finite nuclear size effects are taken into account. We obtain the value $\alpha_0=2.66080(36)$ for the static polarizability, and $\alpha_2=2.850(7)$ and $\alpha_4=4.932(14)$ for the first two polarizability dispersion coefficients (Cauchy moments); all values are in atomic units (a.u.). In the case of static polarizability, our result agrees with the best experimental determination [C. Gaiser and B. Fellmuth, Phys. Rev. Lett. 120, 123203 (2018)], but our estimated uncertainty is significantly larger. For the dispersion coefficients, the results obtained in this work appear to be the most accurate to date overall compared to published theoretical and experimental data. We also calculated the static magnetic susceptibility of the neon atom, needed to obtain the refractive index of gaseous neon. Our result, $\chi_0 = -8.484(19) \cdot 10^{-5}$ a.u., is about 9% larger in absolute value than the recommended experimental value [CRC Handbook of Chemistry and Physics, CRC Press, 2019, p. 4-145].
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