水中抗生素降解用WO3/AgI光催化剂的合成

Tung Mai Hung Thanh, The Do Minh, Hien Tran Thị Thu, Chi Nguyen Thi Phuong Le, Quoc Nguyen Tri, Binh Nguyen Thi Thanh, Mai Nguyen Vu Ngoc, Hiep Phan Phuoc Minh, Cam Nguyen Thi Dieu
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摘要

本文通过固相加热法和改变WO3相对于AgI的摩尔比(1:0.5,1:1,1:2和1:3),在WO3存在下成功合成了AgI,形成AgI/WO3 Z方案异质结。发光光谱表明,在AgI中引入WO3能有效抑制光生载流子的复合。以阿莫西林(AMX)抗生素为有机靶点,在可见光下研究了WO3/AgI在水溶液中的光催化活性。当两种材料耦合形成Z-scheme体系时,WO3/AgI对AXM的光活性大大增强。当WO3/AgI材料摩尔比为1/1时,降解率最高。与纯WO3和AgI相比,WO3/AgI杂化材料由于增强了电子和空穴的传输能力,在降解AMX方面表现出显著提高的可见光诱导光催化活性。
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Synthesis of WO3/AgI photocatalysts applying for degradation of antibiotics in water
In this paper, AgI was successfully synthesized in the presence of WO3 to form AgI/WO3 Z scheme hetero-junction by solid-phase heating method and by varying the WO3 mole ratio (1:0.5, 1:1, 1:2 and 1:3) with respect to the AgI. The PL spectra indicate that the introduction of WO3 to AgI can efficiently suppress the recombination of photo-generated charge carrier. The photocatalytic activity of WO3/AgI was investigated under visible light by using the Amoxicillin (AMX) antibiotic as an organic target in aqueous solution. The WO3/AgI photoactivity for AXM was greatly enhanced when both materials were coupled to form a Z-scheme system. The highest degradation percentage was reached using the WO3/AgI material ratio mole of 1/1. As compared with to the pure WO3 and AgI, the WO3/AgI hybrid material show remarkably improved visible-induced photocatalytic activities in degrading AMX for the enhanced transport ability of electrons and holes.  
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