应用于紫外传感器的PDMS聚合物基硫化土纳米荧光粉的研制

Geeta K. Sharma, Madhushree Bute, S. Jadkar, S. Gosavi
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引用次数: 1

摘要

研究了CaS:Ce在紫外传感器中的应用。采用固态扩散法制备了发光CaS:Ce纳米带。这些纳米带被嵌入PDMS(聚二甲基硅氧烷)中,以提高其抗周围环境潮湿的化学稳定性。发现CaS:Ce和发光- pdms的XRD谱图与标准数据一致。使用Debye Scherrer公式计算的粒径为~ 50 nm。在PDMS中嵌入后,观察到颗粒大小和晶格参数略有变化。利用扫描电镜对制备的样品进行形貌分析,观察到纳米带状结构。该发光-PDMS薄膜表现出与CaS:Ce相似的PL特性(激发和发射),表明PDMS不与CaS:Ce相互作用。提出了一种基于CaS:Ce的200nm-400nm紫外传感器的设计方案。
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Development of alkaline earth sulphide based nanophosphors embedded in PDMS polymer matrix for UV sensor applications
Properties of CaS:Ce were studied for its application in UV sensor. Luminescent CaS:Ce nanobelts were synthesized via solid state diffusion method. These nanobelts were embedded in PDMS (Polydimethylsiloxane) in order to increase chemical stability against moisture in the ambient surrounding. The XRD pattern of CaS:Ce and luminescent-PDMS was found to be in agreement with standard data. Particle size calculated using Debye Scherrer formula was found to be ∼50 nm. A slight variation in particle size and lattice parameter was observed after embedding in PDMS. Morphology of as prepared samples was analysed using SEM and nanobelts like structure was observed. This luminescent-PDMS films showed similar PL characteristics (excitation and emission) as that of CaS:Ce indicating that PDMS does not interact with CaS:Ce. The design for UV sensor using CaS:Ce in 200nm–400nm is proposed.
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