果胶作为天然气水合物抑制剂:avrami模型的应用

B. C. L. D. Silva, B. C. L. D. Silva, B. Fialho, Isabella Leite Ferraz, L. Vitorazi, J. A. Castro
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引用次数: 3

摘要

由于天然气水合物的形成对油气工业的重要性,天然气水合物的研究引起了研究者的关注。天然气水合物会在石油开采过程中中断流动,导致生产损失和安全问题。了解该过程的动力学有助于通过使用通常在较低浓度下应用的动力学抑制剂来延迟水合物的形成。获取该过程的实验数据对于预测水合物形成条件的范围是重要的。本研究将Johnson-Mehl-Avrami-Kolmogorov (JMAK)现象学模型应用于果胶(一种用作动力学抑制剂的天然聚合物)的一组数据,以预测水合物形成的比例。考虑到数据与模型的预测一致,结果表明果胶是潜在的天然水合物抑制剂。
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PECTIN AS NATURAL GAS HYDRATE INHIBITOR: APPLICATION OF THE AVRAMI MODEL
The study of gas hydrate formation has attracted researchers' attention due to the importance of this topic to oil and gas industries. Gas hydrates can interrupt flow during the petroleum extraction resulting in production losses as well as in safety concerns. Understanding the kinetics of the process is useful to delay hydrate formation by using kinetic inhibitors that are applied often at lower concentrations. Acquisition of experimental data on the process is important to predict ranges of conditions for hydrate formation. This work applies the Johnson-Mehl-Avrami-Kolmogorov (JMAK) phenomenological model for a set of data acquired for pectin, a natural polymer used as kinetic inhibitor, to predict the fraction of hydrate formed. Results suggest the use pectin as potential natural hydrate inhibitor, considering that the data are in agreement with the model’s prediction.
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