{"title":"升温速率和粒径对Göynük油页岩热解的影响","authors":"L. Degirmenci, T. Durusoy","doi":"10.1080/00908310490449531","DOIUrl":null,"url":null,"abstract":"Pyrolysis kinetics of (−210 + 149), (−250 + 210) and (−420 + 250) μm particle size Göynük oil shale was investigated under non-isothermal conditions with a heating rate of 10–60 K/min in the 298–1173 K pyrolysis temperature interval under argon atmosphere. The pyrolysis characteristics of the samples were analyzed using TG/DTG curves. Differential thermogravimetric data were analyzed by a model assuming first order kinetics. Minimum activation energy was obtained as 0.6 kJ/mol with 60 K/min in (−210 + 149) μm. It appears from the results that higher heating rate values have a limiting effect on the behavior of the pyrolysis reaction.","PeriodicalId":11841,"journal":{"name":"Energy Sources","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2005-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"23","resultStr":"{\"title\":\"Effect of Heating Rate and Particle Size on the Pyrolysis of Göynük Oil Shale\",\"authors\":\"L. Degirmenci, T. Durusoy\",\"doi\":\"10.1080/00908310490449531\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Pyrolysis kinetics of (−210 + 149), (−250 + 210) and (−420 + 250) μm particle size Göynük oil shale was investigated under non-isothermal conditions with a heating rate of 10–60 K/min in the 298–1173 K pyrolysis temperature interval under argon atmosphere. The pyrolysis characteristics of the samples were analyzed using TG/DTG curves. Differential thermogravimetric data were analyzed by a model assuming first order kinetics. Minimum activation energy was obtained as 0.6 kJ/mol with 60 K/min in (−210 + 149) μm. It appears from the results that higher heating rate values have a limiting effect on the behavior of the pyrolysis reaction.\",\"PeriodicalId\":11841,\"journal\":{\"name\":\"Energy Sources\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2005-07-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"23\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Energy Sources\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1080/00908310490449531\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Energy Sources","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1080/00908310490449531","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Effect of Heating Rate and Particle Size on the Pyrolysis of Göynük Oil Shale
Pyrolysis kinetics of (−210 + 149), (−250 + 210) and (−420 + 250) μm particle size Göynük oil shale was investigated under non-isothermal conditions with a heating rate of 10–60 K/min in the 298–1173 K pyrolysis temperature interval under argon atmosphere. The pyrolysis characteristics of the samples were analyzed using TG/DTG curves. Differential thermogravimetric data were analyzed by a model assuming first order kinetics. Minimum activation energy was obtained as 0.6 kJ/mol with 60 K/min in (−210 + 149) μm. It appears from the results that higher heating rate values have a limiting effect on the behavior of the pyrolysis reaction.
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