H. Patney, Christina Nordlund, A. Moy, H. Rose, B. Young, Michael A. Wilson
{"title":"煤中的富勒烯和纳米管","authors":"H. Patney, Christina Nordlund, A. Moy, H. Rose, B. Young, Michael A. Wilson","doi":"10.1080/10641229909350300","DOIUrl":null,"url":null,"abstract":"Abstract Graphite has normally been used to synthesise fullerenes and nanotubes. However, coal is a cheaper and more suitable industrial material. Because coal is a molecular solid, unlike graphite, the mechanism by which fullerene and nanotubes are formed is different. Moreover, other products such as polyaromatic hydrocarbons (PAHs) and microfibres are also formed. In this review, the mechanism of formation of fullerene and nanotubes from coal is discussed. It is shown that the pathway involved is other than through the C1 intermediate route. The influence of other elements in coal such as hydrogen, oxygen, sulfur and iron is also discussed. It appears that, hydrogen, oxygen, iron and sulfur affect the yield and type of fullerenes and nanotubes formed.","PeriodicalId":12470,"journal":{"name":"Fullerene Science and Technology","volume":"59 1","pages":"941-971"},"PeriodicalIF":0.0000,"publicationDate":"1999-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"8","resultStr":"{\"title\":\"Fullerenes and Nanotubes from Coal\",\"authors\":\"H. Patney, Christina Nordlund, A. Moy, H. Rose, B. Young, Michael A. Wilson\",\"doi\":\"10.1080/10641229909350300\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Abstract Graphite has normally been used to synthesise fullerenes and nanotubes. However, coal is a cheaper and more suitable industrial material. Because coal is a molecular solid, unlike graphite, the mechanism by which fullerene and nanotubes are formed is different. Moreover, other products such as polyaromatic hydrocarbons (PAHs) and microfibres are also formed. In this review, the mechanism of formation of fullerene and nanotubes from coal is discussed. It is shown that the pathway involved is other than through the C1 intermediate route. The influence of other elements in coal such as hydrogen, oxygen, sulfur and iron is also discussed. It appears that, hydrogen, oxygen, iron and sulfur affect the yield and type of fullerenes and nanotubes formed.\",\"PeriodicalId\":12470,\"journal\":{\"name\":\"Fullerene Science and Technology\",\"volume\":\"59 1\",\"pages\":\"941-971\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1999-11-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"8\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Fullerene Science and Technology\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1080/10641229909350300\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Fullerene Science and Technology","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1080/10641229909350300","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Abstract Graphite has normally been used to synthesise fullerenes and nanotubes. However, coal is a cheaper and more suitable industrial material. Because coal is a molecular solid, unlike graphite, the mechanism by which fullerene and nanotubes are formed is different. Moreover, other products such as polyaromatic hydrocarbons (PAHs) and microfibres are also formed. In this review, the mechanism of formation of fullerene and nanotubes from coal is discussed. It is shown that the pathway involved is other than through the C1 intermediate route. The influence of other elements in coal such as hydrogen, oxygen, sulfur and iron is also discussed. It appears that, hydrogen, oxygen, iron and sulfur affect the yield and type of fullerenes and nanotubes formed.
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