用GC-TCD测定HDO产品:获得可靠的分析数据

Oman Zuas, H. Budiman, D. Mansur, Muhammad Rizky Mulyana
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引用次数: 6

摘要

摘要:本文报道了气相色谱-热导检测器(GC-TCD)测定氢脱氧(HDO)气态产物的方法的建立和验证。方法验证参数包括选择性、精密度(重复性和再现性)、准确度、线性度、检出限(LoD)、定量限(LoQ)和鲁棒性。结果表明,该方法无需对样品进行特殊处理,即可从混合物中分离出目标组分H2、CO2、CH4和CO。验证方法具有选择性好、精密度高、准确度高、鲁棒性好等特点。将建立并验证的GC-TCD方法应用于生物油HDO副产物成分的测定,结果表明,所有目标成分的相对标准偏差(RSD)均小于1.0%,表明该方法的开发和验证过程为获得可靠的分析数据提供了可靠的途径。
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Measurement of HDO Products Using GC-TCD: Towards Obtaining Reliable Analytical Data
Abstract This paper reported the method development and validation of a gas chromatography with thermal conductivity detector (GC-TCD) method for the measurement of the gaseous products of hydrodeoxygenation (HDO). The method validation parameters include selectivity, precision (repeatability and reproducibility), accuracy, linearity, limit of detection (LoD), limit of quantitation (LoQ), and robustness. The results showed that the developed method was able to separate the target components (H2, CO2, CH4 and CO) from their mixtures without any special sample treatment. The validated method was selective, precise, accurate, and robust. Application of the developed and validated GC-TCD method to the measurement of by-product components of HDO of bio-oil revealed a good performance with relative standard deviation (RSD) less than 1.0% for all target components, implying that the process of method development and validation provides a trustworthy way of obtaining reliable analytical data.
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