制氢装置的仿真与分析

N. G. Costa, P. Patricio, R. V. Ferreira, M. Neto, M. Cardoso
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引用次数: 2

摘要

高纯氢是炼油厂使用的重要化合物,因为它能够从燃料中去除硫杂质。这种原料通常在制氢装置中通过蒸汽甲烷重整过程生产。由于加氢处理工艺的高等级要求,氢净化步骤是强制性的,通常在吸附柱的电池中进行,称为变压吸附(PSA)。本文的主要目的是介绍一个制氢装置的仿真,重点是PSA过程建模方法。ASPEN PLUS™结合MATLAB®对整个过程进行建模。两个模拟器之间的链接是通过在Excel中开发的VBA (Visual Basic for Applications)宏建立的。这种双向连接并不影响整个过程单元的模拟结果,因为它成功地进行了,并且能够代表令人满意的整体质量和能量平衡,获得纯度为99.8%的氢气。
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SIMULATION AND ANALYSIS OF A HYDROGEN GENERATION UNIT
High Purity Grade Hydrogen is an important compound used in oil refineries due to its capacity for withdrawing sulfur impurities from fuels. This feedstock is commonly produced in Hydrogen Generation Units through a Steam Methane Reforming process. Due to the high-grade requirements in Hydrotreament processes, a hydrogen purification step is mandatory, often conducted in batteries of adsorption columns, known as Pressure Swing Adsorption (PSA). The main objective of this paper is to present the simulation of a Hydrogen Generation Unit, focusing on the PSA process modeling approach. ASPEN PLUS™ was utilized in conjunction with MATLAB® to model the whole process. The link between both simulators was established through VBA (Visual Basic for Applications) macros developed in Excel. This two-way connection did not affect the results obtained by the simulation of the whole process unit, as it was carried out successfully and was able to represent the global mass and energy balances satisfactory, obtaining hydrogen with 99.8% purity.
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