常压等离子体处理聚酯纤维的自然染色

P. S. Vankar, Archana Gangwar
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引用次数: 1

摘要

目的研究等离子体和明矾媒染剂对土耳其红、紫胶、姜黄和儿茶四种天然染料涤纶织物的天然染色效果。采用良性媒染剂明矾对涤纶织物进行了等离子体表面改性。利用天然染料提高涤纶织物的可染性是目前研究的热点。由于表面改性,润湿性增加,从而导致更好的染料吸收。更好的染料吸收和更好的染料粘附是主要目标。设计/方法/方法等离子体介导的自然染色是本研究工作的主要设计。研究了等离子体处理对合成织物涤纶表面改性的影响及其对不同天然染料(土耳其红、紫胶、姜黄和儿茶)染色的影响。明矾作为媒染剂,进一步提高了染料的可染性。重点是利用可持续的天然染料资源改善涤纶织物的天然染色,减少有毒添加剂对废水的污染,实现清洁生产。发现等离子体介导和铝介质染色法对土耳其红、紫胶、姜黄和儿茶四种天然染料均有很好的可染性。等离子体处理样品的色强(K/S)值和牢度性能远优于未处理样品。等离子体和明矾媒染剂的协同作用使涤纶的天然染色非常容易,牢度效果非常好。涤纶经2分钟等离子体处理后,自然染色效果良好。这个过程也很容易被工业采用。由于涤纶是疏水性的,对涤纶织物进行天然染色不是很容易,但有了等离子体介导的天然染色,就成为一种非常简便的染色方法;因此,没有限制。等离子体的使用减少了通常在染色过程中添加的任何化学添加剂的需要。实际意义涤纶织物的天然染色工艺可以扩大到用天然染料进行工业染色。对织物进行等离子体预处理,再用明矾预染,有利于织物的自然染色。使用等离子体代替化学改性剂是一种绿色环保的方法,可以为聚酯织物的可持续着色提供一种清洁的湿法染色方法。原创性/价值等离子体介导和铝媒质天然染色对涤纶的协同作用尚未有任何研究人员尝试过。据作者所知,这是第一次对涤纶织物进行大气等离子体预处理,然后进行明矾染染,显示出非常好的染料吸收和牢度性能,因为在等离子体处理2分钟后,染料分子可以很好地渗透。
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Natural dyeing mediated by atmospheric air pressure plasma treatment of polyester
Purpose The purpose of this study is to check the effectivity of plasma in the natural dyeing of polyester fabric using four natural dyes – Turkey red, Lac, Turmeric and Catechu using plasma and alum mordant. The surface modification on the polyester fabric by plasma along with the use of benign mordant alum is studied. The enhancement of dyeability in polyester fabric with natural dyes is the main focus. Due to surface modification, the wettability increases, which leads to better dye uptake. Better dye uptake and better dye adherence are the main objectives. Design/methodology/approach Plasma-mediated natural dyeing is the main design of this research work. The effect of plasma treatment on surface modification of synthetic fabric polyester and its subsequent effects on their dyeing with different natural dyes, namely, Turkey red, Lac, Turmeric and Catechu are studied. The dyeability was further enhanced by the use of alum as mordant. The main focus is on the betterment of natural dyeing of polyester fabric using sustainable natural dyes resources for dyeing and to reduce wastewater contamination from the usage of toxic additive chemicals for cleaner production. Findings Plasma-mediated and alum-mordanted dyeing method facilitated very good dyeability of all the four natural dyes, namely, Turkey red, Lac, Turmeric and Catechu. Color strength (K/S) values and fastness properties of plasma-treated samples were far better than untreated samples. The synergistic effect of plasma and alum mordanting has made natural dyeing of polyester very easy with very good fastness results. Natural dyeing of polyester after 2 min of plasma treatment showed excellent and desirable results. The process is also easy to be adapted by industries. Research limitations/implications As polyester is hydrophobic, natural dyeing of polyester fabric is not very easy, but with plasma-mediated natural dyeing, it becomes a very facile dyeing method; thus, there are no limitations. Use of plasma has reduced the need for any chemical additives which are usually added during the dyeing process. Practical implications This process of natural dyeing of polyester fabric can be scaled up to industrial dyeing with natural dyes. Plasma pretreatment of the fabric followed by premordanting with alum has facilitated the natural dyeing well. Social implications Use of plasma in place of chemical modifiers can be a green and environmentally friendly approach for sustainable coloration of polyester fabric, providing a clean wet processing for textiles dyeing. Originality/value The synergistic effect of plasma-mediated and alum-mordanted natural dyeing of polyester has not been attempted by any researcher. To the best of the authors’ knowledge, this is for the first time that pretreatment with atmospheric plasma followed by alum mordanting of polyester fabric has shown very good dye uptake and fastness properties as the dye molecules could penetrate well after 2 min of the plasma treatment.
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