线性聚乙烯纳米复合材料介电性能在渗透转变附近的温度依赖动力学

O. Kovalchuk, T. Kovalchuk, Y. Garbovskiy, R.F. Svistilnik, D.V. Pushkarov, L. V. Volokh, O.A. Lagoda, I. V. Oleinikova
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引用次数: 0

摘要

在频率为30 ~ 105 Hz、温度为18 ~ 80℃的条件下,用示波器法研究了含阻燃剂(20 wt.%)和多层碳纳米管(1.5 wt.%)的线性低密度聚乙烯的介电性能。碳纳米管的浓度略高于纳米管的浓度(1%),此时聚合物电导率对纳米管含量的依赖开始发生渗透转变。电导率的频率依赖性可以用两个指数依赖性来近似表示。已经发现,当样品冷却时,介电常数和电导率值的变化与加热时不同。获得了低(102 Hz)和高(104 Hz)频率下电导率的温度依赖性。
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Dynamics of temperature dependence of the dielectric properties of a nanocomposite material based on linear polyethylene in the vicinity of the percolation transition
Within the frequency range of 30 to 105 Hz and temperatures of 18 to 80 °C, the dielectric properties of linear low-density polyethylene with impurities of flame retardant (20 wt.%) and multilayer carbon nanotubes (1.5 wt.%) were investigated using the oscilloscopic method. This concentration value of carbon nanotubes slightly exceeds the concentration of nanotubes (1%), at which the percolation transition begins for the dependence of the polymer electrical conductivity on the content of nanotubes. It has been shown that the frequency dependence of electrical conductivity can be approximated by two exponential dependences. It has been found that when the sample is cooled, changes in the values of dielectric permittivity and electrical conductivity do not occur in the same way as when heated. The temperature dependences of conductivity for low (102 Hz) and high (104 Hz) frequencies have been obtained.
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