GTAW热时效对奥氏体不锈钢Ni包层显微组织和硬度的影响

Kun Yu, Xianwu Shi, Zhijun Li, Chun Li, Shuangjian Chen, Xingtai Zhou
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摘要

钍熔盐堆(TMSR)具有固有安全性、燃料循环简化、发电效率高等特点,是目前最有发展前途的第四代核反应堆之一。然而,TMSR的结构材料必须面对高温环境和严重的熔氟盐腐蚀的挑战。虽然UNS N10003合金在TMSR中具有优异的性能,但该合金的高成本降低了TMSR的经济性。虽然奥氏体不锈钢具有优异的高温强度和较低的成本,但其在熔融氟盐中的耐腐蚀性较差。因此,本工作的目的是在奥氏体不锈钢上采用钨极气体保护焊(GTAW)对Ni包层进行防腐,并研究热时效对包层组织和硬度的影响。采用一系列表征方法分别研究了焊接态和热时效条件下的元素分布和偏析、界面和熔覆层的析出相行为以及微观组织演变。对焊态和热时效条件下熔覆层的硬度变化进行了测试和讨论。
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Effects of Thermal Ageing on Microstructure and Hardness of Ni Cladding on Austenitic Stainless Steel by GTAW
As one of the most promising Generation IV nuclear reactors, thorium molten salt reactor (TMSR) possesses inherent safety, simplified fuel cycle and high power generation efficiency. However, the structure material of TMSR must encounter challenges of high-temperature environment and serious molten fluoride salts corrosion. Although the UNS N10003 alloy has excellent performance in TMSR, the high cost of this alloy reduces the economy of TMSR. Although the austenitic stainless steel possesses excellent high temperature strength and lower cost, it exhibits poor corrosion resistance in molten fluoride salts. Therefore, the purpose of this work is using Ni cladding on austenitic stainless steel by gas tungsten arc welding (GTAW) for corrosion protection and investigating the effects of thermal ageing on microstructure and hardness of cladding. The elements distribution and segregation, the precipitates behavior and the microstructure evolution of interface and cladding layer under as-welded and thermal ageing conditions were studied by a series of characterization methods respectively. The hardness evolution of claddings under as-welded and thermal ageing conditions were tested and discussed.
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