改性木质素对水溶液中Cr(III)和Cr(VI)离子的吸附

A. Demirbaş
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引用次数: 46

摘要

本研究的目的是从改性木质素的生物质来源中研究廉价而有效的金属离子吸附剂,以提供这些吸附剂作为现有商业材料的替代品。研究了木屑改性木质素的Cr(III)和Cr(VI)结合性能。在290 K下,木质素对Cr(VI)和Cr(III)离子的最大吸附量分别为9.3 mg/g和25.0 mg/g。随着溶液pH值从2.0增加到6.0,Cr(III)离子对木质素的吸附量增加,在pH值为4.5 ~ 5.5之间吸附效果最佳。在330 K温度下,Cr(VI)在240 min的最大吸附率为39.5,Cr(III)在240 min的最大吸附率为67.8。
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Adsorption of Cr(III) and Cr(VI) Ions from Aqueous Solutions on to Modified Lignin
The aim for this research is to study inexpensive and effective metal ion adsorbents from biomass sources of modified lignin to offer these adsorbents as replacements for existing commercial materials. The Cr(III) and Cr(VI) binding properties of modified lignin from wood sawdust were studied. The maximum amounts of adsorption are 9.3 and 25.0 mg/g lignin for Cr(VI) and Cr(III) ions for 240 min at 290 K, respectively. As the pH of the solution increases from 2.0 to 6.0, Cr(III) ions show an increase in adsorption to the lignin with optimum adsorption occurring between pH 4.5 and 5.5. The maximum adsorption percentage is 39.5 for Cr(VI) for 240 min at 330 K, and is 67.8 for Cr(III) for 240 min at 330 K.
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