相T, Pb/sub - 1-x/Ca/sub -x/ TiO/sub - 3/单晶的x线图

V. V. Eremkin, V. Smotrakov, L.E. Balyunis, S. I. Shevtsova, A. Kozakov
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引用次数: 0

摘要

利用单晶光学和x射线显微分析数据,在室温至770 K范围内建立了Pb/sub - 1-x/Ca/sub -x/ TiO/sub - 3/ (0/spl les/x/spl les/0.62)固溶体体系的T相x线图。除了典型的PbTiO/ sub3 /铁电四方相和准电立方相外,还发现了两个铁电和非铁电相,它们具有伪单斜晶胞畸变,也作为两个额外的四方相,其中至少有一个是非铁电的,并确定了它们的确切稳定性极限。
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Phase T,x-diagram of Pb/sub 1-x/Ca/sub x/TiO/sub 3/ single crystals
Phase T,x-diagram of the Pb/sub 1-x/Ca/sub x/TiO/sub 3/ (0/spl les/x/spl les/0.62) solid solution system has been constructed in the range from room temperature to 770 K using data of single crystal optical studies and X-ray microanalysis. Besides the typical for PbTiO/sub 3/ ferroelectric tetragonal and paraelectric cubic phases, two ferro- and non-ferroelectric ones having the pseudomonoclinic unit cell distortions also as two additional tetragonal phases, at least one of which is confidently non-ferroelectric, have been found and their exact stability limits have been determined.
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