CdO和CdO- zno复合纳米线:合成、表征及乙醇气体响应

A. Kamble, N. Harale, P. Patil, B. Sinha, K. Chung
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引用次数: 4

摘要

采用化学浴沉积法制备了ZnO掺杂的纯CdO薄膜,研究了其乙醇传感性能。在高碱性条件下,以醋酸镉为镉源,醋酸锌为锌包合源,进行沉积。然后在723K下对这些薄膜进行退火,研究其形貌、光学和气敏响应,以了解ZnO添加的影响。复合膜的光学响应有趣地描述了CdO和ZnO分别在550 nm和360nm左右的可见光区存在单独的吸收特征,从而证实了复合结构的形成。添加ZnO后,表面光滑的CdO纳米线明显转变为珠状纳米线。CdO- zno复合薄膜的CdO线的总直径从60 nm左右减小到40 nm左右。这使得CdO-ZnO复合薄膜的乙醇气敏响应从39%显著提高到61%。
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CdO and CdO-ZnO composite nanowires: Synthesis, characterization and ethanol gas response
A pure and ZnO added CdO thin films are prepared by chemical bath deposition to study their ethanol sensing properties. The depositions were carried out in a highly alkaline condition where in cadmium acetate was used as a source of cadmium while zinc acetate was added as the source of Zn inclusion. These films were subsequently annealed at 723K and studied for its morphological, optical and gas sensing response to understand the effect of ZnO addition. The optical response for the composite film interestingly depicted the existence of separate absorption signature for CdO and ZnO in visible region at around 550 nm and 360nm respectively, thereby confirming the formation of composite structure. The smooth surfaced CdO nano-wires apparently got transformed in to beaded nano wires with the addition of ZnO. The overall diameter of the CdO wires decreased from around 60 nm to approximately 40 nm for CdO-ZnO composite films. This has remarkably enhanced the ethanol gas sensing response from 39% to 61% for the CdO-ZnO composite thin film.
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