水活化镁电池的放电行为

I. Nakatsugawa, Y. Chino, H. Nakano
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引用次数: 4

摘要

水活化镁电池在能量储存和照明方面具有几个有利的特性。本章研究了一种由二氧化锰阴极和镁合金阳极组成的、水滴活化的便携式镁电池。在恒流负载下监测阳极和阴极电位及其电化学阻抗,以评估含水量、电池堆叠和放电周期的影响。结果表明,放电行为最初受水耗尽控制,随后阴极反应停止,阳极积聚Mg(OH) 2。分析了堆积电池导致阳极效率低的问题,并提出了解决的对策。提出了几种提高电池性能的方法。
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Discharge Behavior of Water-Activated Magnesium Battery
Water-activated magnesium batteries possess several favorable attributes for energy storage and lighting sources. In this chapter, a portable-sized magnesium battery which consisted of MnO 2 cathodes and magnesium alloy anodes, being activated by drops of water, was investigated. The anode and cathode potential as well as their electrochemical impedance under a constant current load was monitored to evaluate the effect of water content, cell stacking, and discharging cycles. It was revealed that the discharge behavior was initially controlled by the depletion of water, followed by the cease of cathode reac - tion and the accumulation of Mg(OH) 2 at anode. The problem of low anode efficiency caused by stacking cells was analyzed, and its countermeasure was proposed. Several approaches to improve the battery performance were also presented.
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