{"title":"c60富勒烯与二烯橡胶自由基的反应性研究。2在温和的热条件下与顺式1,4-聚异戊二烯的反应性","authors":"F. Cataldo","doi":"10.1081/FST-100107153","DOIUrl":null,"url":null,"abstract":"Evidences about the reactivity of cis-1,4-polyisoprene (natural and synthetic origin) with C60 are presented by TGA data and by FT-IR and UV-VIS spectroscopy. At 190°C under nitrogen C60 fullerene causes the crosslinking cis-1,4-polyisoprene. The proposed resulting structure is a three-dimensional network where C60 represents the knots and the rubber chain fragments the filaments connecting the knots.","PeriodicalId":12470,"journal":{"name":"Fullerene Science and Technology","volume":"103 1","pages":"515 - 524"},"PeriodicalIF":0.0000,"publicationDate":"2001-08-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"10","resultStr":"{\"title\":\"ON THE REACTIVITY OF C60 FULLERENE WITH DIENE RUBBER MACRORADICALS. II. THE REACTIVITY WITH CIS-1,4-POLYISOPRENE UNDER MILDER THERMAL CONDITIONS\",\"authors\":\"F. Cataldo\",\"doi\":\"10.1081/FST-100107153\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Evidences about the reactivity of cis-1,4-polyisoprene (natural and synthetic origin) with C60 are presented by TGA data and by FT-IR and UV-VIS spectroscopy. At 190°C under nitrogen C60 fullerene causes the crosslinking cis-1,4-polyisoprene. The proposed resulting structure is a three-dimensional network where C60 represents the knots and the rubber chain fragments the filaments connecting the knots.\",\"PeriodicalId\":12470,\"journal\":{\"name\":\"Fullerene Science and Technology\",\"volume\":\"103 1\",\"pages\":\"515 - 524\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2001-08-31\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"10\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Fullerene Science and Technology\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1081/FST-100107153\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Fullerene Science and Technology","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1081/FST-100107153","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
ON THE REACTIVITY OF C60 FULLERENE WITH DIENE RUBBER MACRORADICALS. II. THE REACTIVITY WITH CIS-1,4-POLYISOPRENE UNDER MILDER THERMAL CONDITIONS
Evidences about the reactivity of cis-1,4-polyisoprene (natural and synthetic origin) with C60 are presented by TGA data and by FT-IR and UV-VIS spectroscopy. At 190°C under nitrogen C60 fullerene causes the crosslinking cis-1,4-polyisoprene. The proposed resulting structure is a three-dimensional network where C60 represents the knots and the rubber chain fragments the filaments connecting the knots.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
