溶胶-凝胶膜:铝合金防腐涂层

E. Gonzalez, N. Vejar, R. Solís, L. Muñoz, M. Encinas, M. Páez
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引用次数: 5

摘要

用于航空工业的铝合金易受腐蚀。解决这个问题的办法是碱铬酸盐材料,这种材料一直受到严格的管制和限制。替代方案的发展始于20世纪70年代和21世纪头十年,当时建立了一些潜在的方法。溶胶-凝胶法是其中一种方法,在金属衬底上沉积薄的氧化层。一个重要的方面是各种氧化物之间可能的组合和有机化合物的掺入以改善薄膜的性能;此外,这允许添加抑制剂和纳米材料,使这种方法成为一种有趣且通用的获得涂层的方法。在本章中,我们将描述通过溶胶-凝胶合成的涂层在金属表面防腐中的重要性。本文还讨论了改性溶胶-凝胶聚合物薄膜和杂化体系涂层的优缺点,以及化学表征方法和评价涂层力学性能的可行性。
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Sol-Gel Films: Corrosion Protection Coating for Aluminium Alloy
Aluminum alloys used in aeronautical industry are susceptible to corrosion. The solu- tion to this problem is base chromate materials, which have been heavily regulated and restricted. The development of alternatives begins in the 1970s and the 2000s, where some potential methodologies were established. The sol-gel process is one of these methods, in which thin oxide layers are deposited on the metal substrate. An important aspect is the fact of possible combinations among types of oxides and the incorporation of an organic compound to improve the performance of the films; moreover, this allows the addition of inhibitors and nanomaterials, making this method an interesting and versatile way to obtain a coating. In this chapter, we will describe the importance of the use of coating synthesized via sol-gel in the corrosion protection of metal surfaces. The advantages and disadvantages of using modified sol-gel polymer films and hybrid system coatings will also be discussed, as well as the methodologies for the chemical characterization and the feasibility of evaluating the mechanical properties of the coatings.
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