芒果木纳米纤维素纤维的合成与表征

J. K. Prasannakumar, G. Prakash, B. Basavarajappa, B. Suresh
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摘要

农业生物质是目前地球上纤维素的主要天然来源。经化学处理后,获得韧性、良好的生物相容性和较高的热稳定性等特性。在这项研究中,纳米纤维素是从芒果木(Mangifera indica)一种大量可用的农业生物质中提取的。对纤维素进行碱处理,然后漂白去除木质素、半纤维素、果胶和蜡。采用绿色溶剂离子液体(1-丁基-3-甲基咪唑氯([Bmim] Cl))对纤维素进行超声和离心溶解,得到纳米纤维素。FT-IR光谱证实了纤维素的官能团和向纳米纤维素的显著转化。用XRD表征了合成的纳米纤维素的结晶度。得到的表面结构和尺寸由SEM和TEM表征。TEM图像显示,合成的纳米纤维素的尺寸在27.33 ~ 34.85 nm之间。用热重热分析/差热分析证实了纳米纤维素的热稳定性。热稳定性研究表明,合成的纳米纤维素在473.8℃下表现出优异的热稳定性。将农业废弃物有效转化为增值材料是通过更环保的途径实现的。
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Synthesis and Characterization of Mango Wood Nanocellulose Fibers
Agricultural biomasses are the prominent natural sources of cellulose currently available on the planet. When this was treated chemically, this acquire the properties such as toughness, good biocompatibility, and higher thermal stability. In this study, Nanocellulose was extracted from Mango wood (Mangifera indica) a largely available agricultural biomass. The cellulose was alkali-treated followed by bleaching to remove lignin and hemicellulose, pectins, and waxes. The green solvent i.e Ionic liquid (1-butyl-3-methylimidazolium chloride ([Bmim] Cl) was used to dissolve cellulose to yield Nanocellulose through sonication and centrifugation. The functional groups and significant conversion of cellulose to nanocellulose are confirmed by FT-IR spectra. The crystallinity of synthesized nanocellulose is illustrated by XRD. The surface architecture and size obtained are represented by SEM and TEM monographs. The TEM images show the synthesized nanocellulose has a dimension between 27.33 to 34.85 nm. The thermal stability of the obtained nanocellulose was evidenced using TGA/DTA. The thermal studies records that synthesized nanocellulose shows superior thermal stability up to 473.8°C. The efficient conversion of agricultural waste into value added material is achieved through a greener pathway.
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