赤泥合成沸石材料对水溶液中砷酸盐的吸附研究

H. Pham, Ha M. Nguyen
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摘要

n Rai (Tay Nguyen)赤泥是铝土矿氧化铝生产的废渣,赤泥的主要成分是氧化铁和其他金属氧化物SiO2、Al2O3,赤泥中的铝和二氧化硅被用来合成沸石材料。以赤泥为原料,加入Si,采用水热法合成沸石材料,Si和Al分别为RM-ZeO-Si和RM-ZeO-Si/Al。采用x -射线、EDX、BET和FT-IR研究了沸石材料的结构。结果表明,所合成的分子式为Na8(Al6Si6O24)S. 4h2o中含有一个孙复S原子的新型分子筛。研究了两种材料对砷酸盐的吸附性能,根据Langmuir模型,RM ZeO-Si和RM ZeO-Si/Al对砷酸盐的最大吸附量分别为7.63 mg/g和5.81 mg/g,其最大吸附量均高于原Tay Nguyen赤泥的吸附量(2.30 mg/g)。
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Study on the adsorption of arsenate in aqueous solution by zeolite material synthesized from Tay Nguyen red mud
Tân Rai (Tay Nguyen) red mud is the waste from alumina production of bauxit ore. The composition of red mud contains mainly the iron oxide and other metals oxide as SiO2, Al2O3…The aluminum and silica in red mud was used to synthesize the zeolite material. The zeolite material was synthesized by the hydrothermal method from red mud by adding Si which was RM-ZeO-Si and RM-ZeO-Si/Al for both Si and Al added. The structure of zeolite material studied by X-Ray, EDX, BET and FT-IR. The results showed that the synthesized zeolite was likely the new kind one with one sunfua S atom in the formular Na8(Al6Si6O24)S.4H2O. The absorption arsenate was studied on both materials, the maximum adsorption capacity of arsenate by Langmuir model was 7.63 mg/g and 5.81 mg/g for RM ZeO-Si and RM ZeO-Si/Al, the maximum adsorption capacity was higher than the adsorption ablility of original Tay Nguyen red mud (2.30 mg/g).
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