dlc涂层NiTi合金在血清蛋白存在下的腐蚀行为

R. Hang, Shengli Ma, P. Chu
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引用次数: 26

摘要

采用电弧增强磁溅射(AEMS)技术在镍钛基体上沉积了类金刚石(DLC)涂层。采用开路电位(OCP)、电化学阻抗谱(EIS)和动电位极化测量,研究了血清蛋白、牛血清白蛋白(BSA)和纤维蛋白原(Fib)对37℃磷酸缓冲盐水(PBS)溶液中dlc涂层NiTi合金腐蚀行为的影响。结果表明,DLC涂层可以增强NiTi合金的耐蚀性,特别是BSA的存在可以使OCP向正方向移动,增加极化电阻,降低腐蚀电流密度,提高击穿电位。纤维蛋白原的存在表现出类似的效果,但不如BSA显著。最后,讨论了产生这些结果的机理。
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Corrosion behavior of DLC-coated NiTi alloys in the presence of serum proteins
Diamond-like carbon (DLC) coatings was deposited on NiTi substrates by arc enhanced magnetic sputtering (AEMS) system. The effect of serum proteins, bovine serum albumin (BSA) and fibrinogen (Fib) on the corrosion behavior of DLC-coated NiTi alloys in phosphate buffer saline (PBS) solution at 37°C was investigated using open circuit potential (OCP), electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization measurements. The results showed that DLC coatings could enhance the corrosion resistance of NiTi alloys, especially in the presence of BSA, which could move the OCP to positive direction, increase the polarization resistance, lower the corrosion current density and enhance the breakdown potential. The presence of fibrinogen showed the similar effect but less notable than BSA. Finally, the mechanism leading to these results were discussed.
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