{"title":"新型氟氧化物的结构和介电性能","authors":"Xiukai Cai, Liang-ying Zhang, X. Yao","doi":"10.1109/ISAF.1994.522442","DOIUrl":null,"url":null,"abstract":"The structure of solid solution Bi/sub 1.5/(Zn/sub 1-x/Li/sub x/)Nb/sub 1.5/(O/sub 7-x/F/sub x/) obtained by substitution of oxygen by fluorine in the oxide Bi/sub 1.5/ZnNb/sub 1.5/O/sub 7/ is cubic pyrochlore for 0/spl les/x/spl les/0.15. For 0.80/spl les/x/spl les/1.00, a distorted modification with low symmetry results, while the mixed phases of the above two are formed for other values of x between 0.15 and 0.80. The temperature dependences of the dielectric constants have been studied, and a dielectric anomaly at low temperatures (less than 100/spl deg/C) has been observed.","PeriodicalId":20488,"journal":{"name":"Proceedings of 1994 IEEE International Symposium on Applications of Ferroelectrics","volume":"5 1","pages":"604-606"},"PeriodicalIF":0.0000,"publicationDate":"1994-08-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"The structure and dielectric properties of new oxyfluorides\",\"authors\":\"Xiukai Cai, Liang-ying Zhang, X. Yao\",\"doi\":\"10.1109/ISAF.1994.522442\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The structure of solid solution Bi/sub 1.5/(Zn/sub 1-x/Li/sub x/)Nb/sub 1.5/(O/sub 7-x/F/sub x/) obtained by substitution of oxygen by fluorine in the oxide Bi/sub 1.5/ZnNb/sub 1.5/O/sub 7/ is cubic pyrochlore for 0/spl les/x/spl les/0.15. For 0.80/spl les/x/spl les/1.00, a distorted modification with low symmetry results, while the mixed phases of the above two are formed for other values of x between 0.15 and 0.80. The temperature dependences of the dielectric constants have been studied, and a dielectric anomaly at low temperatures (less than 100/spl deg/C) has been observed.\",\"PeriodicalId\":20488,\"journal\":{\"name\":\"Proceedings of 1994 IEEE International Symposium on Applications of Ferroelectrics\",\"volume\":\"5 1\",\"pages\":\"604-606\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1994-08-07\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Proceedings of 1994 IEEE International Symposium on Applications of Ferroelectrics\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1109/ISAF.1994.522442\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Proceedings of 1994 IEEE International Symposium on Applications of Ferroelectrics","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1109/ISAF.1994.522442","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
The structure and dielectric properties of new oxyfluorides
The structure of solid solution Bi/sub 1.5/(Zn/sub 1-x/Li/sub x/)Nb/sub 1.5/(O/sub 7-x/F/sub x/) obtained by substitution of oxygen by fluorine in the oxide Bi/sub 1.5/ZnNb/sub 1.5/O/sub 7/ is cubic pyrochlore for 0/spl les/x/spl les/0.15. For 0.80/spl les/x/spl les/1.00, a distorted modification with low symmetry results, while the mixed phases of the above two are formed for other values of x between 0.15 and 0.80. The temperature dependences of the dielectric constants have been studied, and a dielectric anomaly at low temperatures (less than 100/spl deg/C) has been observed.
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