聚偏氟乙烯与含c60的聚(甲基丙烯酸乙酯)、聚(丙烯酸甲酯)或聚(丙烯酸乙酯)的混溶性

Jia-Xing Zheng, S. Goh, S. Y. Lee
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引用次数: 5

摘要

将C60掺入到聚甲基丙烯酸乙酯、聚丙烯酸甲酯和聚丙烯酸乙酯中。研究了聚偏氟乙烯(PVDF)与含c60聚合物的混相性。PVDF与所有六种含c60的聚合物样品均可混溶,如熔体的光学清晰度和每种共混物中存在单一玻璃化转变温度所示。采用熔点下降法对不同共混体系的聚合物-聚合物相互作用参数进行了评价。
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MISCIBILITY OF POLY(VINYLIDENE FLUORIDE) WITH C60-CONTAINING POLY(ETHYL METHACRYLATE), POLY(METHYL ACRYLATE), OR POLY(ETHYL ACRYLATE)
C60 was incorporated onto poly(ethyl methacrylate), poly(methyl acrylate) and poly(ethyl acrylate). The miscibility of poly(vinylidene fluoride) (PVDF) with the C60-containing polymers was examined. PVDF is miscible with all the six C60-containing polymer samples as shown by the optical clarity of the melt and the existence of a single glass transition temperature in each blend. The polymer-polymer interaction parameters of various blend systems were evaluated by the melting point depression method.
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