水的发光振荡再现了水氢原子对自旋对的周期性变化

J. Morré, Matthew C. Pharris, R. Pendleton, D. Morré, S. Gudkov, S. Zakharov
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引用次数: 3

摘要

通过快速傅立叶分析,每隔1秒采集一次激光增强水的发光数据,在蓝绿色区域显示出同步的正弦振荡模式,周期长度为18.6 min。振荡模式再现了先前归因于水氢原子对对核自旋对交替的振荡模式。由此产生的光发射与假设相一致,即水发光是在周期性的等对核自旋对相互转换期间达到的最高和最低能态之间的能量转移期间释放能量的结果。18.8 min的周期长度与之前基于FTIR光谱测量发现的约18 min的振荡周期一致,该振荡周期是基于对正对对核自旋对变化的测量,也由足以驱动NADH氧化的氧化还原电位变化引起。
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Oscillations in Water Luminescence Recapitulate Periodic Changes Attributed to Ortho-Para Spin Pairs of Water Hydrogens
Luminescence data from water, enhanced by laser illumination, collected at 1 sec intervals exhibited patterns of synchronized sinusoidal oscillations of light emission in the blue-green region with a period length of 18.6 min when evaluated by Fast Fourier analysis. The oscillatory patterns recapitulate those attributed previously to alternation of ortho-para nuclear spin pairs of water hydrogens. The resultant light emissions are consistent with the hypothesis that water luminescence is the result of the discharge of energy during the transition between the highest and the lowest energy states attained during the periodic ortho-para nuclear spin pair interconversions. The period length of 18.8 min agrees with the previously found oscillatory period of about 18 min based on FTIR spectroscopic measurements of ortho to para nuclear spin pair alternations also given by changes in redox potential sufficient to drive NADH oxidation.
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