{"title":"氯化铝配合物的光谱和结构。第四部分:氯化铝高级配合物的结构","authors":"D. E. Jones, J. Wood","doi":"10.1039/J19710003135","DOIUrl":null,"url":null,"abstract":"The complexes AlCl3,2Me2O,AlCl3,1·5MeCN, AlCl3,2MeCN, and AlCl31·5HCO2Me have been examined by i.r. and Raman spectroscopy; model calculations support a trigonal-bipyramidal five-co-ordinate structure for AlCl3,2Me2O but ionic structures are suggested for the others. AlCl3,2MeCN has uncombined MeCN in the crystal lattice.","PeriodicalId":17321,"journal":{"name":"Journal of The Chemical Society A: Inorganic, Physical, Theoretical","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"3","resultStr":"{\"title\":\"The spectra and structure of aluminium chloride complexes. Part IV. Structure of higher complexes of aluminium chloride\",\"authors\":\"D. E. Jones, J. Wood\",\"doi\":\"10.1039/J19710003135\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The complexes AlCl3,2Me2O,AlCl3,1·5MeCN, AlCl3,2MeCN, and AlCl31·5HCO2Me have been examined by i.r. and Raman spectroscopy; model calculations support a trigonal-bipyramidal five-co-ordinate structure for AlCl3,2Me2O but ionic structures are suggested for the others. AlCl3,2MeCN has uncombined MeCN in the crystal lattice.\",\"PeriodicalId\":17321,\"journal\":{\"name\":\"Journal of The Chemical Society A: Inorganic, Physical, Theoretical\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1971-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"3\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Chemical Society A: Inorganic, Physical, Theoretical\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/J19710003135\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society A: Inorganic, Physical, Theoretical","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/J19710003135","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
The spectra and structure of aluminium chloride complexes. Part IV. Structure of higher complexes of aluminium chloride
The complexes AlCl3,2Me2O,AlCl3,1·5MeCN, AlCl3,2MeCN, and AlCl31·5HCO2Me have been examined by i.r. and Raman spectroscopy; model calculations support a trigonal-bipyramidal five-co-ordinate structure for AlCl3,2Me2O but ionic structures are suggested for the others. AlCl3,2MeCN has uncombined MeCN in the crystal lattice.
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