纳米银在水处理中的应用

Zenaida Guerra Que, J. G. Torres, H. Pérez-Vidal, M. A. Rocha, Juan C. Arévalo Pérez, I. López, D. D. L. C. Romero, Alejandra Reyna, J. C. P. Sosa, A. A. S. Pavón, Jorge Hernández
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引用次数: 13

摘要

近年来,纳米银的开发及其在废水处理中的应用已成为研究的热点。主要适用于农药、重金属、微生物三大污染物的去除。各种合成技术已经报道了制备和表征纳米银。本研究首先采用沉积沉淀法合成了负载在ZrO2和ZrO2- ceo2上的Ag纳米粒子,然后通过氧化还原法依次合成了负载在ZrO2和ZrO2- ceo2上的Ag- au。对催化剂湿式氧化甲基叔丁基醚和苯酚的性能进行了评价。CWAO是一种用于处理有机污染物的液相工艺,工作温度为100-325℃,压力为5-200 bar。采用总有机碳(TOC)和高效液相色谱(HPLC)评价催化剂的选择性和效率。理想情况下,污染物完全矿化成二氧化碳和水是最好的。
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Application of Silver Nanoparticles for Water Treatment
In recent past development of silver nanoparticles and their application in the treatment of wastewaters is becoming a major area of research. It is mainly applicable to the removal of three major pollutants like pesticides, heavy metals, and microorganisms. Variety of synthesis techniques have been reported for preparation and characterization of silver nanoparticles. In our research, we synthesized Ag nanoparticles supported on ZrO2 and ZrO2-CeO2 by a “deposit-precipitation method” as the first step and later sequentially synthesized Ag-Au supported on ZrO2 and ZrO2-CeO2 by Redox method. Catalysts were evaluated in catalytic wet air oxidation (CWAO) of methyl tert-butyl ether and phenol. The CWAO is a liquid phase process for the treatment of organic pollutants operating at temperatures in the range of 100–325°C at 5–200 bar pressures. The selectivity and efficient of catalysts were evaluated by total organic carbon (TOC) and high-performance liquid chromatograph (HPLC). Ideally, the total mineralization of pollutants into CO2 and H2O is preferred.
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