紫外光led照明用BaxSryLizSiO4:Ce3+, Mn2+荧光粉的光致发光性能

Yisen Lin, Z. Xiong, L. Hong, H. Xue, Laura Chen
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摘要

采用部分液相法合成了一系列Ce3+, Mn2+共掺杂BaxSryLizSiO4:Ce3+, Mn2+荧光粉。详细研究了Ba/Sr比、Ce/Mn比和锂含量对BaxSryLizSiO4:Ce3+, Mn2+ (BSLS:Ce, Mn)荧光粉发射光谱的影响。结果表明,BaxSryLizSiO4:Ce3+, Mn2+ (BSLS:Ce, Mn)荧光粉分别在410nm波长附近和620nm波长附近发射蓝光和红光。随着Sr/Ba比的增加,BSLS:Ce, Mn的颜色由橙色变为红色。随着Mn/Ce比的增加,蓝色发射强度降低,红色发射强度增强。当锂含量为15 mol%时,荧光体的发射强度最强。
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Photoluminescence properties of BaxSryLizSiO4:Ce3+, Mn2+ phosphors for NUV-LED lighting
A series of Ce3+, Mn2+ codoped BaxSryLizSiO4:Ce3+, Mn2+ phosphors were synthesized by partially liquid-phase method. The effects of Ba/Sr ratio, Ce/Mn ratio and lithium content on the emission spectra of the BaxSryLizSiO4:Ce3+, Mn2+ (BSLS:Ce, Mn) phosphors were investigated in details, which showed blue emission around 410nm wavelength and red emission at about 620nm wavelength, respectively. With the increasing of Sr/Ba ratio, the color of BSLS:Ce, Mn was changed from orange to red. However, the intensity of blue emission was reduced and red emission was enhanced with an incensement of Mn/Ce ratio. The strongest intensity of emission for the phosphor was obtained at Li content of 15 mol%.
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