细胞石膏的特性及其在技术上的应用

T.Б. Никуличева, В. С. Захвалинский, E.A. Пилюк, И.С. Никулин, В В Вязьмин, M.В. Мишунин, M.Ю. Саенко, O.A. Tельпова, Н.И. Aлфимова, T.A. Eрина
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摘要

目前,利用技术过程的副产品和以生产废料的形式积累的材料作为功能材料的问题变得越来越重要。我们研究了两组样本。第一组成为空气湿度传感器新材料的基础,该材料是从柠檬酸生产的废料中获得的。制备了掺杂硫酸铜(CuSO4)的柠檬酸石膏(二水合硫酸钙,即CaSO4)样品。研究了三种厚度样品的阻抗随相对湿度的变化规律。测量了复合电阻和相对介电常数对相对湿度的频率依赖性。从柠檬酸石膏中得到的第二组样品是由CaSO4晶须组成的粉末。CaSO4晶须用于制备环氧树脂基复合材料。在样品的拉伸和压缩应力的研究中记录了复合材料性能的改进。本文展示了(CaSO4)0.95 - (CuSO4)0.05作为一种新型空气湿度传感器材料的实际应用可能性,以及环氧树脂与CaSO4晶须复合材料力学性能的改善。
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Свойства цитрогипса и возможности его применения в технике
At present, the problem of using as functional materials such materials that are a by-product of technological processes and accumulate in the form of production waste is becoming more relevant. We have studied two groups of samples. The first group became the basis for a new material for the air humidity sensor, which was obtained from the waste products of citric acid production. Samples of citrogypsum (calcium sulfate dihydrate, i.e. CaSO42H2O) doped with copper sulfate (CuSO45H2O) were prepared. The dependence of the impedance on the relative humidity of samples of three thicknesses was carried out. The frequency dependences of complex resistance and relative permittivity on relative humidity are measured. The second group of samples obtained from citrogypsum was a powder consisting of CaSO42H2O whiskers. Whiskers CaSO42H2O were used to create composites based on epoxy resin. An improvement in the properties of the composite was recorded in the study of tensile and compressive stresses of the samples. This article shows the possibility of practical application of (CaSO42H2O)0.95–(CuSO45H2O)0.05 as a new air humidity sensor material and improvement of the mechanical properties of the composite based on epoxy resin and CaSO42H2O whiskers.
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