草酸锌作为商用锂离子电池绿色负极材料的初步研究

M. Arinawati, A. P. Hutama, E. Apriliyani, M. Ikhsanudin, C. Yudha
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引用次数: 1

摘要

锂离子电池具有高能量密度,是新能源和可再生能源发电厂的重要储能材料。然而,商用锂离子电池的负极材料,如石墨和Li4Ti5O12,由于需要高温处理,被认为不太环保,也不经济。本研究首次采用温和温度沉淀法制备草酸锌,并将其作为正极材料应用于商用锂离子电池。采用XRD、FTIR、SEM等方法对所制得的草酸锌的理化性质进行了表征。考察了前驱体浓度的影响。充放电分析表明,草酸锌作为正极材料的放电容量为25 mAh/g。
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Zinc Oxalate as a Green Anode Material for Commercial Li-Ion Batteries: a Preliminary Study
Li ion batteries is a crucial energy storage for new and renewable energy (NRE)-based power plant due to its high energy density. However, the anode materials of commercial Li-ion batteries such as graphite and Li4Ti5O12 are considered less eco-friendly due to it requirement of high temperature processing which is also uneconomical. In this research, for the first time ever, zinc oxalate was prepared via mild temperature precipitation process and applied as anode material in commercial Li-ion batteries. XRD, FTIR and SEM analysis were conducted to examine the physical and chemical properties of the as obtained zinc oxalate. The effect of precursor concentration was investigated. Charge-discharge analysis shows that zinc oxalate dihydrate as anode material delivered a discharge capacity of 25 mAh/g.
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