{"title":"WO3/g-C3N4纳米复合材料的赝电容性能","authors":"Oluwafunmilola Ola, Yu Chen, Yanqiu Zhu, D. Grant","doi":"10.1109/NAP51885.2021.9656569","DOIUrl":null,"url":null,"abstract":"Hexagonal tungsten oxide (WO<inf>3</inf>) holds great promise as an electrode material for pseudocapacitors due to its earth abundance, low cost, multiple oxidation states, high packing density (>7 g cm<sup>-3</sup>) and electrochemical reversibility. Here, we present the development of flexible electrodes consisting of WO<inf>3</inf> nanoflowers supported on graphitic carbon nitride (g-C<inf>3</inf>N<inf>4</inf>) foams. The WO<inf>3</inf>/g-C<inf>3</inf>N<inf>4</inf> electrodes were prepared via a facile solvothermal approach followed by carbonization. The resulting WO<inf>3</inf>/g-C<inf>3</inf>N<inf>4</inf> electrodes have demonstrated excellent performance with specific capacitance of 1130 F g<sup>-1</sup> at 0.5 A g<sup>-1</sup> and good cyclic stability of 95% after 4,000 cycles in 0.5M H<inf>2</inf>SO<inf>4</inf> electrolyte.","PeriodicalId":6735,"journal":{"name":"2021 IEEE 11th International Conference Nanomaterials: Applications & Properties (NAP)","volume":"62 1","pages":"1-4"},"PeriodicalIF":0.0000,"publicationDate":"2021-09-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Pseudocapacitive Performance of WO3/g-C3N4 Nanocomposites\",\"authors\":\"Oluwafunmilola Ola, Yu Chen, Yanqiu Zhu, D. Grant\",\"doi\":\"10.1109/NAP51885.2021.9656569\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Hexagonal tungsten oxide (WO<inf>3</inf>) holds great promise as an electrode material for pseudocapacitors due to its earth abundance, low cost, multiple oxidation states, high packing density (>7 g cm<sup>-3</sup>) and electrochemical reversibility. Here, we present the development of flexible electrodes consisting of WO<inf>3</inf> nanoflowers supported on graphitic carbon nitride (g-C<inf>3</inf>N<inf>4</inf>) foams. The WO<inf>3</inf>/g-C<inf>3</inf>N<inf>4</inf> electrodes were prepared via a facile solvothermal approach followed by carbonization. The resulting WO<inf>3</inf>/g-C<inf>3</inf>N<inf>4</inf> electrodes have demonstrated excellent performance with specific capacitance of 1130 F g<sup>-1</sup> at 0.5 A g<sup>-1</sup> and good cyclic stability of 95% after 4,000 cycles in 0.5M H<inf>2</inf>SO<inf>4</inf> electrolyte.\",\"PeriodicalId\":6735,\"journal\":{\"name\":\"2021 IEEE 11th International Conference Nanomaterials: Applications & Properties (NAP)\",\"volume\":\"62 1\",\"pages\":\"1-4\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2021-09-05\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"2021 IEEE 11th International Conference Nanomaterials: Applications & Properties (NAP)\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1109/NAP51885.2021.9656569\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"2021 IEEE 11th International Conference Nanomaterials: Applications & Properties (NAP)","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1109/NAP51885.2021.9656569","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
摘要
六方氧化钨(WO3)具有稀土丰度高、成本低、多种氧化态、高密度(7 g cm-3)和电化学可逆性等优点,作为赝电容器电极材料具有广阔的应用前景。在这里,我们提出了由石墨氮化碳(g-C3N4)泡沫支撑的WO3纳米花组成的柔性电极的发展。采用简单的溶剂热法和炭化法制备了WO3/g-C3N4电极。所制备的WO3/g-C3N4电极在0.5 A g-1时的比电容为1130 F -1,在0.5 m H2SO4电解液中循环4000次后的循环稳定性为95%。
Pseudocapacitive Performance of WO3/g-C3N4 Nanocomposites
Hexagonal tungsten oxide (WO3) holds great promise as an electrode material for pseudocapacitors due to its earth abundance, low cost, multiple oxidation states, high packing density (>7 g cm-3) and electrochemical reversibility. Here, we present the development of flexible electrodes consisting of WO3 nanoflowers supported on graphitic carbon nitride (g-C3N4) foams. The WO3/g-C3N4 electrodes were prepared via a facile solvothermal approach followed by carbonization. The resulting WO3/g-C3N4 electrodes have demonstrated excellent performance with specific capacitance of 1130 F g-1 at 0.5 A g-1 and good cyclic stability of 95% after 4,000 cycles in 0.5M H2SO4 electrolyte.