丙烯酸酯三元共聚物基涂料抗碳化性能评价

Youssef L. Nashed, F. Zahran, M. Youssef, M. Mohamed, A. M. Mazrouaa
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摘要

本研究的目的是研究基于合成聚合物的抗碳化涂层如何很好地保护钢筋混凝土结构免受混凝土碳化。采用自由基聚合的方法,制备了一种表面活性剂稳定的丙烯酸酯三元共聚物乳液。采用热重分析、最小成膜温度、傅里叶红外光谱和粒径分布对制备的水基丙烯酸酯三元共聚物乳液进行了表征。采用制备的丙烯酸酯三元共聚物乳液的比例分别为35%、45%和55%,形成了抗碳化涂层。抗拉强度、拉伸应变、伸长率、裂缝桥接能力、二氧化碳渗透性、氯离子扩散、平均拉脱附着力、水蒸气透过性、光泽度、耐湿擦洗性、QUV/耐候性和储存稳定性是抗碳化涂层的特点。结果配制的丙烯酸酯三元共聚物乳液在CO2渗透性、cl扩散、裂缝桥接、拉脱附着力和水蒸气透过性等方面提高了抗碳化涂层的性能。所制得的丙烯酸酯三元共聚物乳液的性能优于其商业对应物。为了保护混凝土中嵌入的钢材免受腐蚀,提高混凝土的使用寿命,在水泥表面涂上一层基于合成丙烯酸酯三元共聚物乳液的抗碳化涂层。社会意义除了从建筑物倒塌中拯救生命外,它还可以长期维护基础设施。以合成丙烯酸酯三元共聚物乳液为基础的抗碳化涂料,对环境无害,可以阻止二氧化碳和氯化物的进入,而二氧化碳和氯化物是混凝土中钢材腐蚀的主要原因。
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Performance evaluation of acrylate terpolymer based coating on anti-carbonation
Purpose The purpose of this study is to examine how well reinforced concrete structures can be shielded against concrete carbonation using anti-carbonation coatings based on synthetic polymer. Design/methodology/approach Applying free radical polymerization, an acrylate terpolymer emulsion that a surfactant had stabilized was created. A thermogravimetric analysis, minimum film-forming temperature, Fourier transform infrared spectroscopy and particle size distribution are used to characterize the prepared eco-friendly water base acrylate terpolymer emulsion. Using three different percentages of the acrylate terpolymer emulsion produced, 35%, 45% and 55%, the anti-carbonation coating was formed. Tensile strength, tensile strain, elongation, crack-bridging ability, carbon dioxide permeability, chloride ion diffusion, average pull-off adhesion strength, water vapor transmission, gloss, wet scrub resistance, QUV/weathering and storage stability are the characteristics of the anti-carbonation coating. Findings The formulated acrylate terpolymer emulsion enhances anti-carbonation coating performance in CO2 permeability, Cl-diffusion, crack bridging, pull-off adhesion strength and water vapor transmission. The formed coating based on the formulated acrylate terpolymer emulsion performed better than its commercial counterpart. Practical implications To protect the steel embedded in concrete from corrosion and increase the life span of concrete, the surface of cement is treated with an anti-carbonation coating based on synthetic acrylate terpolymer emulsion. Social implications In addition to saving lives from building collapse, it maintains the infrastructure for the long run. Originality/value The anti-carbonation coating, which is based on the synthetic acrylate terpolymer emulsion, is environmentally benign and stops the entry of carbon dioxide and chlorides, which are the main causes of steel corrosion in concrete.
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