三氯化砷三甲胺、AsCl3、NMe3的晶体结构

M. Webster, S. Keats
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引用次数: 7

摘要

通过x射线单晶衍射对该化合物进行了检测,发现该化合物在Z= 4的P21/c空间群中,在尺寸为a= 6.14, b= 10.33, c= 14.85 a, β= 107·0°的晶胞中结晶。该结构由离散的AsCl3,NMe3分子组成,可以认为是基于三角双锥体砷配位,并将图像估计的三维数据精确到r0·083。
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Crystal structure of arsenic trichloride–trimethylamine, AsCl3,NMe3
The title compound has been examined by single-crystal X-ray diffraction and crystallises in the space group P21/c with Z= 4 in a unit cell of dimensions a= 6·14, b= 10·33, c= 14·85 A, and β= 107·0°. The structure consists of discrete AsCl3,NMe3 molecules which may be considered to be based on trigonal bipyramidal arsenic co-ordination and the photographically estimated three-dimensional data were refined to R 0·083.
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