稻壳制二氧化硅副产品的利用方法

Еlena M. Gotlib, Thi Phuong Mai Ha, Nadezhda V. Shilnikova
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摘要

利用稻壳(RH)作为生产二氧化硅(DC)的原料的现代技术的发展是相关的。然而,在从RH中获得DC的过程中,通常使用酸和碱的溶液。因此,寻找合理的方法来再生这些液体,并利用排放到大气中的废气,以解决环境保护问题就变得非常重要。在RH法合成DC的过程中,产生了固体碳、盐酸和氧化钠的液、废气等废弃物。对于后者的利用,采用吸收净化法是有效的,其基础是液体试剂从其与空气的混合物中吸收有毒气体和蒸汽。所产生的污泥可以有效地用作填充物,用于制造路面(例如沥青)。所产生的酸性废水可用于中和碱性溶液。中和后,除了排放到环境中,这些废物还可以用作化肥(因为它们含有氯化钠)。碳可以用于生产有效的吸附剂,例如,在环境紧急情况下用于消除石油泄漏。稻壳制备的二氧化硅是环氧聚合物的有效填料,可提高环氧聚合物的硬度、耐磨性和抗摩擦性能。它提供了固化过程的加速和填充材料更密集的交联结构的形成。二氧化硅改性作用的性质不取决于稻壳燃烧的温度,它只影响所达到效果的大小。
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Ways to utilize by-products in the production of silica from rice husk
The development of modern technologies for the use of rice husk (RH) as a raw material for the production of silicon dioxide (DC) is relevant. However, in the process of obtaining DC from RH, as a rule, solutions of acids and alkalis use. This makes it important to search for rational ways to regenerate these liquids and utilize exhaust gas emissions into the atmosphere in order to solve the problems of environmental protection. In the synthesis of DC based on RH, the following wastes are obtained: solid – carbon, liquid – solutions of hydrochloric acid and sodium oxide, exhaust gases. For utilization of the latter, it is effective to use the absorption purification method, based on the absorption by liquid reagents of toxic gases and vapors from their mixtures with air. The resulting sludge can be effectively used as a filler, in the manufacture of pavements (for example, asphalt). The resulting acidic wastewater can be used to neutralize alkaline solutions. After neutralization, in addition to discharging into the environment, these wastes can be used as chemical fertilizers (since they contain sodium chloride). Carbon can be used in the production of effective sorbents used, for example, to eliminate oil spills in environmental emergencies. Silicon dioxide obtained from rice husk is an effective filler of epoxy polymers, increasing their hardness, wear resistance and improving antifriction characteristics. It provides acceleration of the curing process and the formation of more denser cross linked structure of filled materials. The nature of the modifying action of silicon dioxide does not depend on the temperature of burning rice husk, which affects only the magnitude of the effects achieved.
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