Ariel V. Melendres, R. Cruz, Mel Bryan L. Espenilla, A. M. Monsada
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引用次数: 1
摘要
研究了聚酰胺环氧高吸水性聚合物(SAP)的吸光性能及其在碳钢缓蚀中的应用。SAP的类型为聚丙烯酸钠,交联密度相对较低。SAP的细颗粒与环氧树脂混合,随后加入聚酰胺硬化剂,使环氧树脂发生聚合,而SAP分散在聚合物基体中。在此之前,对用于该应用的SAP在纯水和氯化钠溶液中的吸收性能进行了测试。复合材料,即固化环氧树脂与SAP,同样检查其吸收性能。结果表明,与纯水相比,纯SAP在氯化钠溶液中的吸光度降低,复合材料的吸光度也有相同的变化趋势,但吸光度要低得多。将复合材料涂在厚度为0.7mm、厚度为40 mm × 100 mm的碳钢表面,进行了防腐性能测试。复合材料的抗腐蚀性能优于不含SAP的对照材料聚酰胺环氧树脂,其良好的耐腐蚀性能可归因于SAP的自修复性能。
Absorbency and Corrosion Inhibition Property of Polyamide Epoxy and Superabsorbent Polymer Composite Material
Polyamide epoxy containing superabsorbent polymer (SAP) was investigated for its absorbency property and its application in the inhibition of corrosion in carbon steel. The type of SAP was sodium polyacrylate with relatively low crosslinking density. Fine particles of SAP was mixed with epoxy resin and subsequently the polyamide hardener was added allowing the polymerization of epoxy resin to occur while the SAP is dispersed within the polymer matrix. Prior to this, the SAP used for this application was examined in terms of its absorbency property in pure water and in sodium chloride solutions. The composite material, i.e. cured epoxy with SAP, was likewise examined for its absorbency property. Results showed decreased absorbency of pure SAP in sodium chloride solution compared with pure water, and the same trend was exhibited in the composite material but with much lower absorbency. The composite material was applied on the surface of carbon steel of 40 mm x 100 mm and thickness of 0.7mm and tested for anticorrosion property. The composite material gave better results than the control material of polyamide epoxy without SAP. The better corrosion resistance exhibited by the composite materials could be attributed to the self-healing property of SAP.
期刊介绍:
Chemical Engineering Transactions (CET) aims to be a leading international journal for publication of original research and review articles in chemical, process, and environmental engineering. CET begin in 2002 as a vehicle for publication of high-quality papers in chemical engineering, connected with leading international conferences. In 2014, CET opened a new era as an internationally-recognised journal. Articles containing original research results, covering any aspect from molecular phenomena through to industrial case studies and design, with a strong influence of chemical engineering methodologies and ethos are particularly welcome. We encourage state-of-the-art contributions relating to the future of industrial processing, sustainable design, as well as transdisciplinary research that goes beyond the conventional bounds of chemical engineering. Short reviews on hot topics, emerging technologies, and other areas of high interest should highlight unsolved challenges and provide clear directions for future research. The journal publishes periodically with approximately 6 volumes per year. Core topic areas: -Batch processing- Biotechnology- Circular economy and integration- Environmental engineering- Fluid flow and fluid mechanics- Green materials and processing- Heat and mass transfer- Innovation engineering- Life cycle analysis and optimisation- Modelling and simulation- Operations and supply chain management- Particle technology- Process dynamics, flexibility, and control- Process integration and design- Process intensification and optimisation- Process safety- Product development- Reaction engineering- Renewable energy- Separation processes- Smart industry, city, and agriculture- Sustainability- Systems engineering- Thermodynamic- Waste minimisation, processing and management- Water and wastewater engineering