{"title":"青铜时代铜锭的显微结构,锑含量高","authors":"R. Haubner, S. Strobl","doi":"10.1515/pm-2022-1004","DOIUrl":null,"url":null,"abstract":"Abstract The Cu ingot from Velem contains approximately 10 wt.% Sb, 4.5 wt.% As, 1.2 wt.% S and Ag, as well as other trace elements in an amount below 0.2 percent by weight. A Cu2S band running virtually across the entire width of the ingot suggests that it was formed by the reaction of molten Cu with antimonite (Sb2S3). Remarkably, the generated cutting surface was not copper-colored but had a silvery appearance which, however, can be attributed to the high Sb content. The metallographic examinations revealed a very inhomogeneous structural composition of the ingot. Large areas consist of dendritically solidified Cu, while the interdendritic areas are characterized by mixtures of different phases of the elements Cu-Sb-As-S.","PeriodicalId":20360,"journal":{"name":"Practical Metallography","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2022-11-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Microstructure of an extraordinary Bronze Age copper ingot with a high antimony content\",\"authors\":\"R. Haubner, S. Strobl\",\"doi\":\"10.1515/pm-2022-1004\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Abstract The Cu ingot from Velem contains approximately 10 wt.% Sb, 4.5 wt.% As, 1.2 wt.% S and Ag, as well as other trace elements in an amount below 0.2 percent by weight. A Cu2S band running virtually across the entire width of the ingot suggests that it was formed by the reaction of molten Cu with antimonite (Sb2S3). Remarkably, the generated cutting surface was not copper-colored but had a silvery appearance which, however, can be attributed to the high Sb content. The metallographic examinations revealed a very inhomogeneous structural composition of the ingot. Large areas consist of dendritically solidified Cu, while the interdendritic areas are characterized by mixtures of different phases of the elements Cu-Sb-As-S.\",\"PeriodicalId\":20360,\"journal\":{\"name\":\"Practical Metallography\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2022-11-27\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Practical Metallography\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1515/pm-2022-1004\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Practical Metallography","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1515/pm-2022-1004","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
摘要
来自Velem的铜锭含有约10%的Sb, 4.5%的As, 1.2%的S和Ag,以及其他微量元素,其重量比小于0.2%。Cu2S带几乎贯穿了铸锭的整个宽度,这表明它是由熔融Cu与锑矿(Sb2S3)反应形成的。值得注意的是,生成的切割表面不是铜色的,而是具有银色的外观,然而,这可以归因于高Sb含量。金相检验显示铸锭的组织成分极不均匀。大面积的枝晶凝固区域由Cu组成,而枝晶间区域则由Cu- sb - as - s元素的不同相混合组成。
Microstructure of an extraordinary Bronze Age copper ingot with a high antimony content
Abstract The Cu ingot from Velem contains approximately 10 wt.% Sb, 4.5 wt.% As, 1.2 wt.% S and Ag, as well as other trace elements in an amount below 0.2 percent by weight. A Cu2S band running virtually across the entire width of the ingot suggests that it was formed by the reaction of molten Cu with antimonite (Sb2S3). Remarkably, the generated cutting surface was not copper-colored but had a silvery appearance which, however, can be attributed to the high Sb content. The metallographic examinations revealed a very inhomogeneous structural composition of the ingot. Large areas consist of dendritically solidified Cu, while the interdendritic areas are characterized by mixtures of different phases of the elements Cu-Sb-As-S.