室温硫化硅橡胶和硅基增强导电复合硅橡胶可靠性研究

Mengke Zhao, Z. Xia, Yongxin Zhu, Xiaohei Liu, F. Guo
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引用次数: 1

摘要

随着信息技术的飞速发展,电磁干扰(EMI)被认为是电子信息产业中一个重要的环境和可靠性问题。由于电磁信号容易受到外界电磁辐射的干扰,因此迫切需要采取有效措施来减少或最终消除电磁干扰。基于这种需求,电磁屏蔽导电硅橡胶引起了人们的广泛关注。在本文中,我们报告了我们对导电聚合物复合材料的基础研究,即在聚合物中加入不同的导电填料以达到所需的导电性。导电高分子复合材料因其成本低、加工工艺简单等优点,在许多领域得到了广泛的应用。为了获得更好的性能,两种主要成分硅橡胶和导电填料都应表现出良好的性能和相容性。本文主要研究室温硫化硅橡胶。提高硅橡胶性能的尝试是基于配方设计和工艺改进的实验努力。通过一系列对比试验,研究了符合要求性能的RTV硅橡胶的配方和工艺。我们采用85°C-85% RH老化、100°C老化和盐雾试验(SST)来研究RTV硅橡胶和导电硅橡胶的可靠性。对服务性能的几个方面进行了测试和表征。
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Study on reliability of room temperature vulcanization silicone rubber and conductive composite silicone rubber reinforced by silica
Electromagnetic interference (EMI) is considered as a crucial environmental and reliability issue in electronic information industries, especially with the rapid development of information technology. Since electromagnetic signals are prone to be interfered by external electromagnetic radiation, it is urgent to take effective measures to reduce, or ultimately eliminate the electromagnetic interference. Electromagnetic shielding conductive silicone rubber hence attracts great attention based on such demands. In this paper, we report our fundamental studies on conductive polymer composite materials, i.e., adding different conductive filler into polymer to achieve required conductivity. Conductive polymer composite materials have been widely used in many different areas owing to its low cost and uncomplicated processing techniques. In order to achieve better performance, the two main components, silicone rubber and conductive filler, should both exhibit good performance and compatibility. This paper is focused on the room temperature vulcanized (RTV) silicone rubber. The attempt to improve the performance of silicone rubber was based on the experimental efforts on formula design as well as processing improvement. The formula and processing of RTV silicone rubber with required performances was investigated from a series of comparative experiments. 85°C-85% RH aging, 100°C aging, and salt spray testing (SST) were different ways we employed to investigate the reliability of RTV silicone rubber and conductive silicone rubber. Several aspects of service performance were tested and characterized.
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