过渡金属二硫代配合物。XX的一部分。铼的二氰-1,2-二硫代配合物

Journal of The Chemical Society A: Inorganic, Physical, Theoretical Pub Date : 1971-01-01 DOI:10.1039/J19710000712

N. Connelly, C. J. Jones, J. McCleverty

{"title":"过渡金属二硫代配合物。XX的一部分。铼的二氰-1,2-二硫代配合物","authors":"N. Connelly, C. J. Jones, J. McCleverty","doi":"10.1039/J19710000712","DOIUrl":null,"url":null,"abstract":"A voltammetric study of the complex previously formulated as [Re{S2C2(CN)2}2]22– has shown that it must be reformulated as [Re{S2C2(CN)2}2]44–, which undergoes one one-electron reduction and two one-electron oxidation processes. Oxidation of [Re{S2C2(CN)2}3]2– with iodine afforded [ReO{S2C2(CN)2}2]–, which may be reduced voltammetrically to a dianion.","PeriodicalId":17321,"journal":{"name":"Journal of The Chemical Society A: Inorganic, Physical, Theoretical","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"8","resultStr":"{\"title\":\"Transition-metal dithiolene complexes. Part XX. Dicyano-1,2-dithiolene complexes of rhenium\",\"authors\":\"N. Connelly, C. J. Jones, J. McCleverty\",\"doi\":\"10.1039/J19710000712\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"A voltammetric study of the complex previously formulated as [Re{S2C2(CN)2}2]22– has shown that it must be reformulated as [Re{S2C2(CN)2}2]44–, which undergoes one one-electron reduction and two one-electron oxidation processes. Oxidation of [Re{S2C2(CN)2}3]2– with iodine afforded [ReO{S2C2(CN)2}2]–, which may be reduced voltammetrically to a dianion.\",\"PeriodicalId\":17321,\"journal\":{\"name\":\"Journal of The Chemical Society A: Inorganic, Physical, Theoretical\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1971-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"8\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Chemical Society A: Inorganic, Physical, Theoretical\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/J19710000712\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society A: Inorganic, Physical, Theoretical","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/J19710000712","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}

引用次数: 8

摘要

对先前分子式为[Re{S2C2(CN)2}2]22 -的配合物进行伏安研究表明，它必须重新分子式为[Re{S2C2(CN)2}2]44 -，经过一次单电子还原和两次单电子氧化过程。[Re{S2C2(CN)2}3]2 -与碘氧化得到[ReO{S2C2(CN)2}2] -，它可以伏安还原为一个离子。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文

微信好友朋友圈 QQ好友复制链接

本刊更多论文

Transition-metal dithiolene complexes. Part XX. Dicyano-1,2-dithiolene complexes of rhenium

A voltammetric study of the complex previously formulated as [Re{S2C2(CN)2}2]22– has shown that it must be reformulated as [Re{S2C2(CN)2}2]44–, which undergoes one one-electron reduction and two one-electron oxidation processes. Oxidation of [Re{S2C2(CN)2}3]2– with iodine afforded [ReO{S2C2(CN)2}2]–, which may be reduced voltammetrically to a dianion.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Journal of The Chemical Society A: Inorganic, Physical, Theoretical

自引率

0.00%

发文量