过渡金属二硫代配合物。XX的一部分。铼的二氰-1,2-二硫代配合物

Journal of The Chemical Society A: Inorganic, Physical, Theoretical Pub Date : 1971-01-01 DOI:10.1039/J19710000712

N. Connelly, C. J. Jones, J. McCleverty

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引用次数: 8

摘要

对先前分子式为[Re{S2C2(CN)2}2]22 -的配合物进行伏安研究表明，它必须重新分子式为[Re{S2C2(CN)2}2]44 -，经过一次单电子还原和两次单电子氧化过程。[Re{S2C2(CN)2}3]2 -与碘氧化得到[ReO{S2C2(CN)2}2] -，它可以伏安还原为一个离子。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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Transition-metal dithiolene complexes. Part XX. Dicyano-1,2-dithiolene complexes of rhenium

A voltammetric study of the complex previously formulated as [Re{S2C2(CN)2}2]22– has shown that it must be reformulated as [Re{S2C2(CN)2}2]44–, which undergoes one one-electron reduction and two one-electron oxidation processes. Oxidation of [Re{S2C2(CN)2}3]2– with iodine afforded [ReO{S2C2(CN)2}2]–, which may be reduced voltammetrically to a dianion.

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Journal of The Chemical Society A: Inorganic, Physical, Theoretical

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