{"title":"新型手性杯[4]氮杂冠醚衍生物的简便合成及其对甲醇分子的包结行为","authors":"李正义, 滕明瑜, 马洁洁, 黄吉, 王乐勇, 潘毅","doi":"10.1360/ZB2009-39-4-369","DOIUrl":null,"url":null,"abstract":"本文报道新型手性杯[4]氮杂冠醚衍生物的简便合成. 即在路易斯酸(ZnCl2)催化下, 二氰基取代杯[4]芳烃与各种光学活性的1, 2-氨基醇反应, 高产率得到了手性杯[4]氮杂冠醚衍生物. 该方法具有反应条件温和、操作简便、产率高等特点. 产物的晶体X-衍射及ESI-MS数据表明, 通过主客体之间的O–H···π作用, 杯芳烃上沿的空腔对甲醇分子具有较强的包结作用.","PeriodicalId":49128,"journal":{"name":"Science in China. Series B, Chemistry","volume":"42 1","pages":"369-369"},"PeriodicalIF":0.0000,"publicationDate":"2009-04-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"新型手性杯[4]氮杂冠醚衍生物的简便合成及其对甲醇分子的包结行为\",\"authors\":\"李正义, 滕明瑜, 马洁洁, 黄吉, 王乐勇, 潘毅\",\"doi\":\"10.1360/ZB2009-39-4-369\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"本文报道新型手性杯[4]氮杂冠醚衍生物的简便合成. 即在路易斯酸(ZnCl2)催化下, 二氰基取代杯[4]芳烃与各种光学活性的1, 2-氨基醇反应, 高产率得到了手性杯[4]氮杂冠醚衍生物. 该方法具有反应条件温和、操作简便、产率高等特点. 产物的晶体X-衍射及ESI-MS数据表明, 通过主客体之间的O–H···π作用, 杯芳烃上沿的空腔对甲醇分子具有较强的包结作用.\",\"PeriodicalId\":49128,\"journal\":{\"name\":\"Science in China. Series B, Chemistry\",\"volume\":\"42 1\",\"pages\":\"369-369\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2009-04-20\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Science in China. Series B, Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1360/ZB2009-39-4-369\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Science in China. Series B, Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1360/ZB2009-39-4-369","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
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