亚铁离子与阴离子表面活性剂共同作用下粘胶织物淀粉解退浆的多响应优化

Z. A. Raza, Aisha Rehman, F. Anwar, Naseer Ahmad
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引用次数: 1

摘要

目的研究亚铁离子(Fe2+)和十二烷基硫酸钠(SDS)的存在对灰质粘胶织物退浆过程中淀粉酶活性的影响,为工业应用提供参考。去除淀粉是织物染色和整理前的一个重要步骤。作者倾向于以环保和可持续的方式实现这一目标。设计/方法学/方法采用田口法设计实验,采用灰色关联分析法对实验结果进行分析,优化实验流程。采用标准方案评价了织物的吸湿性、还原糖、弯曲长度、失重、Tegawa额定值和抗拉强度等纺织性能。利用扫描电镜(SEM)、x射线衍射(XRD)和热重分析(TGA)等先进分析技术对对照和优化后的粘胶样品进行了表面化学性质的研究。结果表明,Fe2+浓度和工艺时间是影响粘胶织物淀粉解退浆的主要因素。最佳工艺条件为0.1 mm Fe2+离子、3 mm SDS、80℃、7 pH、30 min。Fe2+离子和SDS的存在促进了粘胶织物的生物退浆。SEM、傅里叶变换红外光谱、XRD和TGA分析结果表明,施胶剂被有效地从织物表面去除。实际意义在某些金属离子和表面活性剂存在的情况下,淀粉酶对粘胶织物进行退浆是一个重要的课题,因为酶可能面临它们,因为它们在水系统中普遍存在。这也可以支持生物退浆和生物洗涤操作在一个浴中完成,从而使纺织品预处理过程既经济又环保。原创性/价值在统计多响应优化下,作者未见Fe2+离子和SDS表面活性剂共同作用下粘胶织物生物退浆的报道。采用传统方法和分析方法对生物粘胶织物进行了研究。
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Multiresponse optimization in amylolytic desizing of viscose fabric in the copresence of ferrous ions and an anionic surfactant
Purpose This study aims to investigate the effect of the copresence of ferrous (Fe2+) ions and sodium dodecyl sulfate (SDS) on the activity of an amylase enzyme during the desizing of greige viscose fabric for potential industrial applications. The removal of starches is an essential step before processing the fabric for dyeing and finishing operations. The authors tend to accomplish it in eco-friendly and sustainable ways. Design/methodology/approach The experiments were designed under the Taguchi approach, and the results were analyzed using grey relational analysis to optimize the process. The textile properties of absorbency, reducing sugars, bending length, weight loss, Tegawa rating and tensile strength were assessed using the standard protocols. The control and optimized viscose specimens were investigated for certain surface chemical properties using advanced analytical techniques including scanning electron microscopy (SEM), X-ray diffraction (XRD) and thermal gravimetric analysis (TGA). Findings The results demonstrate that the Fe2+ concentration and process time were the main influencing factors in the amylolytic desizing of viscose fabric. The optimized process conditions were found to be 0.1 mm Fe2+ ions, 3 mm SDS, 80°C, 7 pH and 30 min process time. The copresence of Fe2+ ions and SDS promoted the biodesizing of viscose fabric. The SEM, Fourier transform infrared spectroscopy, XRD and TGA results demonstrated that the sizing agent has efficiently been removed from the fabric surface. Practical implications The amylase desizing of viscose fabric in the presence of certain metal ions and surfactants is a significant subject as the enzyme may face them due to their prevalence in the water systems. This could also support the biodesizing and bioscouring operations to be done in one bath, thus making the textile pretreatment process both economical and environmentally sustainable. Originality/value The authors found no report on the biodesizing of viscose fabric in the copresence of Fe2+ ions and the SDS surfactant under statistical multiresponse optimization. The biodesized viscose fabric has been investigated using both conventional and analytical approaches.
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