食品腐败代谢物对紫胶染料颜色变化动力学的影响:草莓腐败监测的验证

Priyanka Sakare, S. Giri
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引用次数: 1

摘要

目的研究紫胶染料对醛类、二氧化碳等食品腐败代谢物的变色动力学响应,为其在智能食品包装中的潜在应用提供依据。设计/方法/方法采用紫外可见光谱法研究染料溶液的颜色变化。染料溶液在528 nm处的吸光度(离子化峰)与在488 nm处的吸光度(非离子化峰)之比研究了染料的颜色变化。用零级反应动力学和一级反应动力学研究了吸光度比(A528/A488)随时间的变化。为验证草莓品质监测的研究结果,制备了紫胶染料指示剂。发现slac染料在酸性介质中呈橙红色,在碱性介质中呈紫色。染料对苯甲醛的反应符合零级反应动力学,对二氧化碳的反应符合一阶反应动力学。醇类、酮类和含硫化合物的染料溶液未见颜色变化。在验证部分,当草莓变质时,指示剂标签的颜色由紫色变为橙色。本研究拓展了紫胶染料作为传感试剂在食品智能包装中果蔬变质或成熟检测的应用领域。
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Color change kinetics of lac dye as influenced by some food spoilage metabolites: validation for spoilage monitoring of strawberries
Purpose The purpose of this paper was to study the color change kinetics of lac dye in response to aldehydes, carbon dioxide and other food spoilage metabolites for its potential application in intelligent food packaging. Design/methodology/approach UV–Vis spectroscopy was used to study the color change of dye solution. Ratio of absorbance of dye solution at 528 nm (peak of ionized form) to absorbance at 488 nm (peak of unionized form) was used to study the color change. Color change kinetics was studied in terms of change in absorbance ratio (A528/A488) with time using zero and first-order reaction kinetics. Lac dye-based indicator was prepared to validate the result of study for monitoring quality of strawberries. Findings Lac dye was orange-red in acidic medium and purple in alkaline medium. Color change of dye in response to benzaldehyde followed zero-order reaction kinetics, whereas for carbon dioxide first-order model was found best. No color change of dye solution was observed for alcohols, ketones and sulfur compounds. In the validation part, the color of the indicator label changed from purple to orange when the strawberries spoiled. Originality/value The study expands application area for lac dye as sensing reagent in intelligent food packaging for spoilage or ripeness detection of fruits and vegetables.
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