{"title":"锑-121 Mössbauer一些锑的氯络合物的光谱","authors":"T. Birchall, B. Valle, E. Martineau, J. Milne","doi":"10.1039/J19710001855","DOIUrl":null,"url":null,"abstract":"The 121Sb Mossbauer spectra of a number of chloroantimony salts have been examined. The presence of both SbIII and SbV in Rb2SbCl6 is confirmed. Extremely large, negative isomer shifts are obtained for [SbIIICl6]3– species and are interpreted in terms of a stereochemically inactive Ione-pair of electrons.","PeriodicalId":17321,"journal":{"name":"Journal of The Chemical Society A: Inorganic, Physical, Theoretical","volume":"38 1","pages":"1855-1857"},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"9","resultStr":"{\"title\":\"Antimony-121 Mössbauer spectroscopy of some chloro-complexes of antimony\",\"authors\":\"T. Birchall, B. Valle, E. Martineau, J. Milne\",\"doi\":\"10.1039/J19710001855\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The 121Sb Mossbauer spectra of a number of chloroantimony salts have been examined. The presence of both SbIII and SbV in Rb2SbCl6 is confirmed. Extremely large, negative isomer shifts are obtained for [SbIIICl6]3– species and are interpreted in terms of a stereochemically inactive Ione-pair of electrons.\",\"PeriodicalId\":17321,\"journal\":{\"name\":\"Journal of The Chemical Society A: Inorganic, Physical, Theoretical\",\"volume\":\"38 1\",\"pages\":\"1855-1857\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1971-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"9\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Chemical Society A: Inorganic, Physical, Theoretical\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/J19710001855\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society A: Inorganic, Physical, Theoretical","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/J19710001855","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Antimony-121 Mössbauer spectroscopy of some chloro-complexes of antimony
The 121Sb Mossbauer spectra of a number of chloroantimony salts have been examined. The presence of both SbIII and SbV in Rb2SbCl6 is confirmed. Extremely large, negative isomer shifts are obtained for [SbIIICl6]3– species and are interpreted in terms of a stereochemically inactive Ione-pair of electrons.
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