石英增强气相光声光谱研究进展

F. Tittel, A. Kosterev, Y. Bakhirkin
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引用次数: 2

摘要

报道了一种检测气体介质中光声信号的新方法。与传统光声光谱(PAS)中使用充满气体的谐振声腔和麦克风不同,该方法还可以使用高Q压电晶体元件来检测声能。石英晶体音叉可作为光声气体传感的谐振换能器元件。最近,我们介绍了一种新的PAS方法,称为石英增强光声光谱(QEPAS)。QEPAS利用了石英晶体极高的品质因子Q。利用谐振频率为32.768 kHz的石英音叉(TF)和工作频率为1.53 /spl μ /m的光纤耦合分布反馈(DFB)二极管激光器进行的气体传感器可行性实验表明,以NH/sub 3/为目标气体,归一化检测限为7.2/spl倍/10/sup -9/ W/Hz/sup 1/2 /。该灵敏度与传统PAS的最佳报告结果在同一范围内。QEPAS的灵敏度限制因子是TF的基本热噪声。
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Recent advances in quartz-enhanced gas-phase photoacoustic spectroscopy
A new approach to detecting photoacoustic signals in gas media is reported. Instead of using a gas-filled resonant acoustic cavity and a microphone as in traditional photoacoustic spectroscopy (PAS) the sound energy can also be detected using a high Q piezoelectric crystal element. Quartz crystal tuning forks can be used as resonant transducer elements for photoacoustic gas sensing. Recently, we introduced a novel approach to PAS called quartz-enhanced photoacoustic spectroscopy (QEPAS). QEPAS takes advantage of the extremely high quality factor Q of quartz crystals. Feasibility experiments of a gas sensor utilizing a quartz tuning fork (TF) resonating at 32.768 kHz and a fiber coupled distributed-feedback (DFB) diode laser operating at 1.53 /spl mu/m have demonstrated a normalized detection limit of 7.2/spl times/10/sup -9/ W/Hz/sup 1/2 / using NH/sub 3/ as the target gas. This sensitivity is in the same range as the best reported result for conventional PAS. The sensitivity limiting factor of QEPAS is the fundamental thermal noise of the TF.
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