Dual-Polymer Fracturing Fluids Provide Major Advantages Over Traditional Fluids

As exploration for oil and gas continues, it becomes necessary to produce from deeper formations, have low permeability, and higher temperature. Unconventional shale formations utilize slickwater fracturing fluids due to the shale’s unique geomechanical properties. On the other hand, conventional formations require crosslinked fracturing fluids to properly enhance productivity. Guar and its derivatives have a history of success in crosslinked hydraulic fracturing fluids. However, they require higher polymer loading to withstand higher temperature environments. This leads to an increase in mixing time and additive requirements. Most importantly, due to the high polymer loading, they do not break completely and generate residual polymer fragments that can plug the formation and reduce fracture conductivity significantly. In this work, a new hybrid dual polymer hydraulic fracturing fluid is developed. The fluid consists of a guar derivative and a polyacrylamide-based synthetic polymer. Compared to conventional fracturing fluids, this new system is easily hydrated, requires fewer additives, can be mixed on the fly, and is capable of maintaining excellent rheological performance at low polymer loadings. The polymer mixture solutions were prepared at a total polymer concentration of 20 to 40 lb/1,000 gal and at a volume ratio of 2:1, 1:1, and 1:2. The fluids were crosslinked with a metallic crosslinker and broken with an oxidizer at 300°F. Testing focused on crosslinker to polymer ratio analysis to effectively lower loading while maintaining sufficient performance to carry proppant at this temperature. HP/HT rheometer was used to measure viscosity, storage modulus, and fluid breaking performance. HP/HT aging cell and HP/HT see-through cell were utilized for proppant settling. FTIR, Cryo-SEM and HP/HT rheometer were also utilized to understand the interaction. Results indicate that the dual polymer fracturing fluid is able to generate stable viscosity at 300°F and 100 s-1. Results show that the dual polymer fracturing fluid can generate higher viscosity compared to the individual polymer fracturing fluid. Also, properly understanding and tuning the crosslinker to polymer ratio generates excellent performance at 20 lb/1,000 gal. The two polymers form an improved crosslinking network that enhances proppant carrying properties. It also demonstrates a clean and controlled break performance with an oxidizer. Extensive experiments were pursued to evaluate the new dual polymer system for the first time. This system exhibits a positive interaction between polysaccharide and polyacrylamide families and generates excellent rheological properties. The major benefit of using a mixed polymer system is to reduce polymer loading. Lower loading is highly desirable because it reduces material cost, eases field operation and potentially lowers damage to the fracture face, proppant pack, and formation.