热电用杂化卤化物钙钛矿薄膜

S. Saini, A. Yonamine, R. Nishio, I. Matsumoto, T. Yabuki, K. Miyazaki
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引用次数: 0

摘要

热电效应可以作为物联网设备的可持续能源。在此基础上,利用自旋镀膜技术在玻璃衬底上制备了有机-无机杂化卤化物-钙钛矿-碘化甲基铵锡薄膜。利用x射线衍射图和扫描电镜对薄膜进行了结构和化学表征。在室温附近测量热电参数。薄膜在100°C下加热5 min,电导率为2.4 S/cm,塞贝克系数为$65 \mu V/K$,功率因数为$1.0 \mu W/m \cdot K^{2}$。这些混合卤化物钙钛矿的热电性能将有助于进一步开发室温下的直接热能收集装置。
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Hybrid-halide perovskite thin films for thermoelectric application
Thermoelectric effect can be a promising candidate as a sustainable energy source for internet of things devices. In this regards, thin films of organic-inorganic hybrid halide-perovskites, Methylamonium tin iodide, were fabricated by spin coating technique on a glass substrate. Thin films were structurally and chemically characterized by x-ray diffraction pattern and scanning electron microscope. Thermoelectric parameters were measured near room temperature. Thin films heated for 5 min at 100°C shows the best performance with electrical conductivity 2.4 S/cm, Seebeck coefficient $65 \mu V/K$ and power factor of $1.0 \mu W/m \cdot K^{2}$. Thermoelectric performance from these hybrid-halide perovskite will help for further development of direct thermal energy harvesting devices near room temperature.
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