一种利用热化学反应的近井增产和去除沉积物的新方法

Abdullah Alharith, Sulaiman Albassam, Thamer Al-Zahrani
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摘要

有机和无机沉积物是油井井筒中的一个重要问题和关注点。本文讨论了一种利用热化学配方的新方法的应用,该方法成功地对有机和无机沉积物产生了影响,作为消除剂,并作为增产液来提高近井地层的渗透率。新配方包括将亚硝酸盐与氨基磺酸混合在目标层的井筒中。这个反应的产物包括热、酸性盐和氮气。反应产生的热量足以液化有机沉积物,酸性盐会解决管内的碳酸盐垢,并增加近井筒区域的渗透率。氮气是惰性气体;它不会影响反应,并有助于在处理后回流到井中。实验结果表明,当这两种化学物质混合时,温度增加了65℃。试验在室温条件下进行,温度达到90℃左右。再将井筒温度提高65℃,就足以融化沥青质和蜡,酸性盐可以解决碳酸盐结垢问题。因此,这种混合物可以同时消除有机和无机沉积物。经混合反应配方处理后,石灰石样品的渗透率提高了65%。新的热化学配方的独特之处在于同时实现三个目标的潜力;反应产生的热量去除井筒中的有机沉积物,酸性盐处理碳酸盐结垢,提高近井筒区域的渗透率。
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A Novel Approach for Near Wellbore Stimulation and Deposits Removal Utilizing Thermochemical Reaction
Organic and inorganic deposits play a major issue and concern in the wellbore of oil wells. This paper discusses the utilization of a new and novel approach utilizing a thermochemical recipe that shows a successful impact on both organic and inorganic deposits, as an elimination agent, and functions as stimulation fluid to improve the permeability of the near wellbore formation. The new recipe consists of mixing nitrite salt with sulfamic acid in the wellbore at the target zone. The product of this reaction includes heat, acidic salt, and nitrogen gas. The heat of the reaction is enough to liquefy the organic deposits, and the acidic salt will tackle the carbonate scale in the tube and will increase the permeability of the near wellbore area. The nitrogen gas is an inert gas; it will not affect the reaction and will help to flow back the well after the treatment. The experimental work shows an increment in the temperature by 65 °C when mixing the two chemicals. The test was conducted at room conditions and the temperature reached around 90 °C. Adding another 65 °C to the wellbore temperature is enough to melt asphaltene and wax, the acidic salt tackles carbonate scale. As a result, the mixture works on eliminating both the organic and inorganic deposits. The permeability of the limestone sample shows an increment of 65% when treated by the mixture of the reaction recipe. The uniqueness of the new thermochemical recipe is the potential of performing three objectives at the same time; the heat of the reaction removes the organic deposits in the wellbore, the acidic salt tackles carbonate scale, and improves the permeability of the near wellbore zone.
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