模拟电极厚度对电解质和液态水源源的电源性和极性的影响(VRFB)

Satria Pamungkas Panji Kumara, Irvan Fajar Hidayah, Silvi Hadila, Ervinka Felindia, Nikita Syaharani, Mauludi Ariesto Pamungkas, Kurriawan Budi Pranata, Alamsyah Mohammad Juwono, Muhammad Ghufron
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引用次数: 0

摘要

−钒氧化还原液流电池(VRFB)是一种相对较新的二次电池,可作为太阳能电池等可再生能源发电厂的储能系统(ESS)。利用COMSOL Multiphysics软件对二维VRFB单胞进行建模,并采用能思特-普朗克、二次电流分布、三次电流分布和butler - volmer原理对其进行数值模拟。模拟在293、15 K下进行,电极厚度变化为1mm (L1)、2mm (L2)、3mm (L3)、4mm (L4)和5mm (L5)。由模拟结果可知,在各种变化条件下,负极的电解液电位都高于正极,且其分布都有减小的趋势。在充电过程中,收集器附近的表面浓度占主导地位,而在放电过程中则相反。VRFB L1表现出较弱的性能,而VRFB L2在电极表面的电解质电位和物质摩尔浓度方面表现出最好的性能。
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Simulasi Pengaruh Ketebalan Elektroda Terhadap Potensial Elektrolit dan Molaritas Spesies Vanadium Redox Flow Battery (VRFB)
−Vanadium Redox Flow Battery (VRFB) is a relative new type of secondary battery that has ability as Energy Storage System (ESS) for renewable energy power plants such as solar cell. 2D VRFB single cell was modeled using COMSOL Multiphysics software and simulated numerically by using Nernst-Planck, secondary current distribution, tertiary current distribution and Buttler-Volmer principle. Simulation was conducted at 293,15 K, with electrode thickness variations of 1 mm (L1), 2 mm (L2), 3 mm (L3), 4 mm (L4) and 5 mm (L5). According to the simulation results, it is known that electrolyte potential in negative electrode is higher than positive electrode and the distribution is tend to decrease for all variations. Surface concentration near collector is dominant during charging compare inlet position and the reverse phenomenon occur during discharging process. VRFB L1 show weak performance and VRFB L2 show the best performance in term of electrolyte potential and species molarity in the electrode surface.
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