不同过充电电压条件下锂电池失效及微观结构特征

F. Jiang, Wanning Wang, Yilin Chen, D. Liang, Shanjun Mo
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引用次数: 2

摘要

随着锂电池的应用越来越广泛,锂电池火灾也越来越频繁。根据调查,大多数锂电池火灾是由过充引起的。为了研究不同过充电电压下锂电池的失效及金相特征。本文通过设定不同充电电压和使用马弗炉加热,模拟了电池过充火灾过程。记录电池在实验过程中的温度变化和实验现象,并对电池正极帽进行金相分析,比较不同充电电压下锂电池的失效和金相特征。结果表明,锂电池在过充状态下的爆炸是不确定的。充电电压越高,电池升温速率越高,正极帽晶粒尺寸越大,晶界越清晰。本研究为锂电池火灾事故的调查提供了思路,为锂电池火灾痕迹识别的进一步研究奠定了基础。
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Failure and Microstructure Characteristics of Lithium Batteries under Different Overcharging Voltage Conditions
As lithium batteries become more and more widely used, the fire of lithium batteries is becoming more frequent. According to the investigation, most lithium battery fires are caused by overcharge. In order to research the failure and metallographic characteristics of lithium battery under different overcharge voltage. This paper simulates the process of overcharge battery fires by setting different charging voltages and using muffle furnace heating. The temperature changes and experimental phenomena of the battery during the experiment is recorded, and the positive electrode cap of the battery was subjected to metallographic analysis to compare the failure and metallographic characteristics of the lithium battery under different charging voltages. The results show that the explosion of lithium batteries is uncertain under overcharge. The higher the charging voltage, the higher the heating rate of the batteries, the larger the grain size of the positive electrode cap and the clearer the grain boundary. This study provides a way of thinking for the investigation of fire accidents of lithium battery, and lays a foundation for further research on the identification of fire traces of lithium battery.
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