室温咪唑基离子液体作为原油硫化氢脱除剂

A. Miranbeigi, M. Yousefi, M. Abdouss
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引用次数: 6

摘要

原油中H2S含量的测定采用了一种精确的方法,取代了我们之前开发的UOP163方法。通过两种方法对il和清道夫进行评价。第一个是基于可变浓度的ILs作为清除剂(动态方法),第二个是基于在H2S去除过程中固定浓度的清除剂(静态方法)。在静态法中,对三种il进行了实验设计,考察了il的时间、温度和剂量(注射量)三个参数。根据石油终端的运行条件,研究了大范围的时间和温度。用动态法计算il的剂量。结果表明,这些ILs对原油中H2S的还原效果显著,在某些条件下H2S浓度小于1ppm
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Room temperature imidazolium-based ionic liquids as scavengers for hydrogen sulfide removal of crude oil
Determination of H2S amounts in crude oil was performed by a precise method instead of UOP163 that were developed in our pervious works. Evaluation of ILs and scavengers were done by two ways. The first one was based on variable concentration of ILs as the scavenger (dynamic method), and the second one was based on a constant concentration of the scavenger during H2S removal process (static method). In the static method, design of experiments was performed for all three tested ILs and three parameters such as time, temperature, and dosage (injection volume) of ILs were investigated. A wide range of time and temperature was also studied according to operating conditions in petroleum terminals.The dose of ILs was obtained from the dynamic method. According to the obtained results, these ILs had a significant effect on H2S reduction in crude oil, so that H2S concentration in some conditions was less than 1ppm
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