Pub Date : 2024-03-30DOI: 10.24200/amecj.v7.i01.272
Khalil Ibrahim Alabid, H. Nasser
This paper deals with an electrochemical method for the determination of methylene blue (MB) by fabrication of an electrode based on a carbon paste modified with nano-nickel oxide and nitrogen carbon quantum dots (NiO-NCQD), graphene-carbon nitride (g-C3N4), reduced graphene oxide (rGO), and graphite powder and paraffin oil are as a plasticizer. This electrode is used as a working electrode. The analytical method used is cyclic voltammetry (CV), The oxidation-reduction curve of methylene blue was shown using this electrode. It is a quasi-reversible curve, and it works at (pH =1) and the best acid used is HCl a concentration of (0.1M). It was also found that the linear range is within the range of (7.99-31.98 mg L-1). The standard deviation (SD) and relative standard deviation (RSD%) were obtained at (0.361 mg L-1 and 0.294 mg L-1) and (4.52% and 3.68%) for both oxidation and reduction respectively. Retrospective, the limit of quantitative (LOQ) and limit of detection (LOD) were achieved at (99.65%; 99.70%), (0.24 mg L-1; 0.13 mg L-1), and (0.071 mg L-1; 0.039 mg L-1) for both oxidation and reduction respectively. Methylene blue was analyzed by UV-Vis spectrophotometry at (663 nm).
{"title":"Determine methylene blue based on carbon paste electrode modified with nanoparticles of nickel oxide-nitrogen carbon quantum dots and carbon structures by cyclic voltammetry","authors":"Khalil Ibrahim Alabid, H. Nasser","doi":"10.24200/amecj.v7.i01.272","DOIUrl":"https://doi.org/10.24200/amecj.v7.i01.272","url":null,"abstract":"This paper deals with an electrochemical method for the determination of methylene blue (MB) by fabrication of an electrode based on a carbon paste modified with nano-nickel oxide and nitrogen carbon quantum dots (NiO-NCQD), graphene-carbon nitride (g-C3N4), reduced graphene oxide (rGO), and graphite powder and paraffin oil are as a plasticizer. This electrode is used as a working electrode. The analytical method used is cyclic voltammetry (CV), The oxidation-reduction curve of methylene blue was shown using this electrode. It is a quasi-reversible curve, and it works at (pH =1) and the best acid used is HCl a concentration of (0.1M). It was also found that the linear range is within the range of (7.99-31.98 mg L-1). The standard deviation (SD) and relative standard deviation (RSD%) were obtained at (0.361 mg L-1 and 0.294 mg L-1) and (4.52% and 3.68%) for both oxidation and reduction respectively. Retrospective, the limit of quantitative (LOQ) and limit of detection (LOD) were achieved at (99.65%; 99.70%), (0.24 mg L-1; 0.13 mg L-1), and (0.071 mg L-1; 0.039 mg L-1) for both oxidation and reduction respectively. Methylene blue was analyzed by UV-Vis spectrophotometry at (663 nm).","PeriodicalId":7797,"journal":{"name":"Analytical Methods in Environmental Chemistry Journal","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-03-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140361506","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-03-30DOI: 10.24200/amecj.v7.i01.321
Ahmed Jaber Ibrahim
This study aimed to evaluate the potentially toxic effects of trace elements in the blood of Iraqi medical radiography workers by analyzing them through GF-AAS. The study involved 50 male blood radiography workers from the medical imaging field at Al-Shatrah General Hospital in Thi-Qar City, Iraq. All workers were aged between 35-50 years and had worked for less than 10 years. The study compared these workers with 50 healthy men. The study found a significant increase in the levels of Cu, Pb, Cd, and Ca among radiography workers compared to the healthy control group, while Zn and Se levels decreased significantly. Moreover, Specificity and confidence interval (95%) were estimated via the receiver operating characteristic curve (ROC). The study provided conclusive evidence of disturbances in the levels of trace elements in the blood of radiographer workers, which makes them more susceptible to many diseases because of their radiation exposure. which portends the more preventive measures of radiation. The linear range of Cd, Cu, Zn, Se and Pb in human serum were obtained 0.2-6.0 µg dL-1, 6.0-200 µg dL-1, 8.0-200 µg dL-1, 10-250 µg dL-1, 4-120 µg dL-1 by GF-AAS after dilution samples with DW up to 20 (n=10, RSD< 5%).
{"title":"the Determination and evaluation of trace elements in the blood of radiography workers using graphite furnace atomic absorption spectrometry","authors":"Ahmed Jaber Ibrahim","doi":"10.24200/amecj.v7.i01.321","DOIUrl":"https://doi.org/10.24200/amecj.v7.i01.321","url":null,"abstract":"This study aimed to evaluate the potentially toxic effects of trace elements in the blood of Iraqi medical radiography workers by analyzing them through GF-AAS. The study involved 50 male blood radiography workers from the medical imaging field at Al-Shatrah General Hospital in Thi-Qar City, Iraq. All workers were aged between 35-50 years and had worked for less than 10 years. The study compared these workers with 50 healthy men. The study found a significant increase in the levels of Cu, Pb, Cd, and Ca among radiography workers compared to the healthy control group, while Zn and Se levels decreased significantly. Moreover, Specificity and confidence interval (95%) were estimated via the receiver operating characteristic curve (ROC). The study provided conclusive evidence of disturbances in the levels of trace elements in the blood of radiographer workers, which makes them more susceptible to many diseases because of their radiation exposure. which portends the more preventive measures of radiation. The linear range of Cd, Cu, Zn, Se and Pb in human serum were obtained 0.2-6.0 µg dL-1, 6.0-200 µg dL-1, 8.0-200 µg dL-1, 10-250 µg dL-1, 4-120 µg dL-1 by GF-AAS after dilution samples with DW up to 20 (n=10, RSD< 5%).","PeriodicalId":7797,"journal":{"name":"Analytical Methods in Environmental Chemistry Journal","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-03-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140364215","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-03-30DOI: 10.24200/amecj.v7.i01.279
Deeksha Kumari, Yunes M. M. A. Alsayadi, Navni Sharma
It is always a concern to ensure personnel and environment safety in the field of chemistry which has caused to development of green analytical chemistry methods. Green chemistry aims to create an eco-friendly environment in laboratories by using various analytical methods/strategies to reduce the use of toxic solvents which are harmful to humans and the environment. It is a way that protect the environment by using green solvents and methods. Green analytical chemistry is a rapid analytical technique that describes the separation, identification, and quantification of an analyte in drugs, environments, and humans. Various green methodologies such as automation, miniaturization, precipitations, and passivation are utilized in the recovery of solvents and reagents. Green analytical chemistry aims to create an eco-friendly environment in the laboratories by using various analytical methods/strategies to reduce the use of toxic solvents which are harmful to the environment/humans as well as to decrease the amount of waste generated. In this review, we explore different green solvents that can replace other toxic solvents used during extraction processes. In this review, the various extraction methods and analytical techniques used to analyze different components have been discussed.
{"title":"A review: Exploratory analysis of recent advancement in green analytical chemistry application","authors":"Deeksha Kumari, Yunes M. M. A. Alsayadi, Navni Sharma","doi":"10.24200/amecj.v7.i01.279","DOIUrl":"https://doi.org/10.24200/amecj.v7.i01.279","url":null,"abstract":"It is always a concern to ensure personnel and environment safety in the field of chemistry which has caused to development of green analytical chemistry methods. Green chemistry aims to create an eco-friendly environment in laboratories by using various analytical methods/strategies to reduce the use of toxic solvents which are harmful to humans and the environment. It is a way that protect the environment by using green solvents and methods. Green analytical chemistry is a rapid analytical technique that describes the separation, identification, and quantification of an analyte in drugs, environments, and humans. Various green methodologies such as automation, miniaturization, precipitations, and passivation are utilized in the recovery of solvents and reagents. Green analytical chemistry aims to create an eco-friendly environment in the laboratories by using various analytical methods/strategies to reduce the use of toxic solvents which are harmful to the environment/humans as well as to decrease the amount of waste generated. In this review, we explore different green solvents that can replace other toxic solvents used during extraction processes. In this review, the various extraction methods and analytical techniques used to analyze different components have been discussed.","PeriodicalId":7797,"journal":{"name":"Analytical Methods in Environmental Chemistry Journal","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-03-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140361543","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-03-29DOI: 10.24200/amecj.v7.i01.281
Anurag Choudhary, Sardar Singh Poonia
In the study, chitosan functionalized iron oxide incorporated with peanut shell biomass was prepared for potential adsorption of chromium (VI) from an aqueous media. The prepared material was characterized by modern spectroscopic methods for confirming the successful embedding. The adsorption experiments were conducted in batch systems. The experimental data showed robust removal of chromium supported by kinetic and equilibrium studies. The sorption data exhibited a strong agreement with the pseudo-second-order kinetics model, further confirming conformity with the Langmuir isotherm model. Adsorption studies were taken to find the effects of pH and time, reusability, ionic strength and presence of coexisting ions. The maximum sorption capacity was achieved as 14.28 mg g-1 at pH 4 and the optimum contact time was 40 minutes. The background electrolytes have much less effect on uptake efficiency and this green adsorbent can be utilized for up to four cycles. Additionally, a systematic approach was employed to ensure the precision and accuracy of the spectroscopic method. Calibration was linear in the range from 0.5 to 6.0 μg L-1 (R2 > 0.99). The limits of detection (LOD) and quantification (LOQ) were 0.65 μg L-1 and 2.16 μg L-1, respectively. The relative standard deviation (RSD) was 7.62 % (n=7).
{"title":"Chromium desalinization using novel chitosan functionalized iron oxide- biochar composites: Analysis, synthesis, characterization and adsorption performance","authors":"Anurag Choudhary, Sardar Singh Poonia","doi":"10.24200/amecj.v7.i01.281","DOIUrl":"https://doi.org/10.24200/amecj.v7.i01.281","url":null,"abstract":"In the study, chitosan functionalized iron oxide incorporated with peanut shell biomass was prepared for potential adsorption of chromium (VI) from an aqueous media. The prepared material was characterized by modern spectroscopic methods for confirming the successful embedding. The adsorption experiments were conducted in batch systems. The experimental data showed robust removal of chromium supported by kinetic and equilibrium studies. The sorption data exhibited a strong agreement with the pseudo-second-order kinetics model, further confirming conformity with the Langmuir isotherm model. Adsorption studies were taken to find the effects of pH and time, reusability, ionic strength and presence of coexisting ions. The maximum sorption capacity was achieved as 14.28 mg g-1 at pH 4 and the optimum contact time was 40 minutes. The background electrolytes have much less effect on uptake efficiency and this green adsorbent can be utilized for up to four cycles. Additionally, a systematic approach was employed to ensure the precision and accuracy of the spectroscopic method. Calibration was linear in the range from 0.5 to 6.0 μg L-1 (R2 > 0.99). The limits of detection (LOD) and quantification (LOQ) were 0.65 μg L-1 and 2.16 μg L-1, respectively. The relative standard deviation (RSD) was 7.62 % (n=7).","PeriodicalId":7797,"journal":{"name":"Analytical Methods in Environmental Chemistry Journal","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-03-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140366854","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-03-29DOI: 10.24200/amecj.v7.i01.307
Salah Mahdi Saleh, A. A. Abdulwahid, Zaki Nassir Kadhim
This investigation used efficientMWCNTs and their derivatives; MWCNT-Tris, MWCNT-H, MWCNT-Tetra and MWCNT-G, for extraction and removing the Bismarck Brown-Y (BB-Y) by solid phase extraction (SPE). The concentration of BB-Y was measured by UV-Vis spectrophotometer after the SPE technique. The solid phases were analyzed and characterized by utilizing several techniques, including Fourier Transform Infrared Spectroscopy (FTIR), FE-SEM, zeta potential measurement, and X-ray Diffraction (XRD). At optimization conditions, the optimum concentration of the BB-y was obtained at 200 mgL-1 and 300 mg L-1 for MWCNT and MWCNT-Tris, whereas 400 mg L-1 for MWCNT-H, MWCNT-Tetra, and MWCNT-G. Additionally, the optimal pH value was 6.0 for MWCNT-Tris, and it was 10 for MWCNT, MWCNT-H, MWCNT-Tetra, and MWCNT-G. However, the volume of samples was achieved at 25 mL. Furthermore, it was found that the most effective flow rate for the eluting solvent was 0.5 ml min-1. Besides the type and volume of eluents were examined and evaluated. Finally, the present work involved the determination of adsorption capacity using Langmuir and Freundlich isotherm models under ideal conditions. The Langmuir model revealed that the qmax for the MWCNT, MWCNT-tris, MWCNT-H, MWCNT-Tetra, and MWCNT-G was obtained 862.07, 1075.27, 1282.05, 1298.70, and 1333.33 mg g-1, respectively.
{"title":"Solid phase-fabrication of multi-walled carbon nanotubes and their derivatives for efficient extraction and analysis of Bismarck Brown-Y Dye from aqueous solution","authors":"Salah Mahdi Saleh, A. A. Abdulwahid, Zaki Nassir Kadhim","doi":"10.24200/amecj.v7.i01.307","DOIUrl":"https://doi.org/10.24200/amecj.v7.i01.307","url":null,"abstract":"This investigation used efficientMWCNTs and their derivatives; MWCNT-Tris, MWCNT-H, MWCNT-Tetra and MWCNT-G, for extraction and removing the Bismarck Brown-Y (BB-Y) by solid phase extraction (SPE). The concentration of BB-Y was measured by UV-Vis spectrophotometer after the SPE technique. The solid phases were analyzed and characterized by utilizing several techniques, including Fourier Transform Infrared Spectroscopy (FTIR), FE-SEM, zeta potential measurement, and X-ray Diffraction (XRD). At optimization conditions, the optimum concentration of the BB-y was obtained at 200 mgL-1 and 300 mg L-1 for MWCNT and MWCNT-Tris, whereas 400 mg L-1 for MWCNT-H, MWCNT-Tetra, and MWCNT-G. Additionally, the optimal pH value was 6.0 for MWCNT-Tris, and it was 10 for MWCNT, MWCNT-H, MWCNT-Tetra, and MWCNT-G. However, the volume of samples was achieved at 25 mL. Furthermore, it was found that the most effective flow rate for the eluting solvent was 0.5 ml min-1. Besides the type and volume of eluents were examined and evaluated. Finally, the present work involved the determination of adsorption capacity using Langmuir and Freundlich isotherm models under ideal conditions. The Langmuir model revealed that the qmax for the MWCNT, MWCNT-tris, MWCNT-H, MWCNT-Tetra, and MWCNT-G was obtained 862.07, 1075.27, 1282.05, 1298.70, and 1333.33 mg g-1, respectively.","PeriodicalId":7797,"journal":{"name":"Analytical Methods in Environmental Chemistry Journal","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-03-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140367951","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-03-28DOI: 10.24200/amecj.v7.i01.320
Shatha Al-Samarrai
This study involved the development of a novel, cost-effective, fast, and highly sensitive analytical technique for quantifying minimal amounts of the drug famotidine through chemiluminescence. The method is centred around the measurement of energy emitted as a result of the interaction between the drug and Luminol in an alkaline solution; this interaction generates an electronically excited intermediate state, releasing a portion of the system’s energy as photons. The method was sensitive for the analysis of famotidine. The linear calibration curve (LR) is obtained in the range 2-12 mg mL-1, with a high correlation coefficient (R2) of 0.9929. The molecular absorption coefficient (ε) was calculated at 2621×104 L mol-1 cm-1. The method displayed excellent sensitivity with a Sandell’s sensitivity of 1.287×10-5 mg cm-2, the detection limit (LOD) was found to be 0.0314 mg mL-1, and the limit of quantification (LOQ) was 0.0952 mg mL-1. This study found that recovery was obtained at 104 - 96.5 %, and the relative standard deviation (RSD%) was below 1.981%. The results showed that the proposed technique has efficient recovery for measuring famotidine in pharmaceutical preparations.
{"title":"Analytical Method: Determination of famotidine drug using chemiluminescence method","authors":"Shatha Al-Samarrai","doi":"10.24200/amecj.v7.i01.320","DOIUrl":"https://doi.org/10.24200/amecj.v7.i01.320","url":null,"abstract":"This study involved the development of a novel, cost-effective, fast, and highly sensitive analytical technique for quantifying minimal amounts of the drug famotidine through chemiluminescence. The method is centred around the measurement of energy emitted as a result of the interaction between the drug and Luminol in an alkaline solution; this interaction generates an electronically excited intermediate state, releasing a portion of the system’s energy as photons. The method was sensitive for the analysis of famotidine. The linear calibration curve (LR) is obtained in the range 2-12 mg mL-1, with a high correlation coefficient (R2) of 0.9929. The molecular absorption coefficient (ε) was calculated at 2621×104 L mol-1 cm-1. The method displayed excellent sensitivity with a Sandell’s sensitivity of 1.287×10-5 mg cm-2, the detection limit (LOD) was found to be 0.0314 mg mL-1, and the limit of quantification (LOQ) was 0.0952 mg mL-1. This study found that recovery was obtained at 104 - 96.5 %, and the relative standard deviation (RSD%) was below 1.981%. The results showed that the proposed technique has efficient recovery for measuring famotidine in pharmaceutical preparations.","PeriodicalId":7797,"journal":{"name":"Analytical Methods in Environmental Chemistry Journal","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-03-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140369027","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-03-28DOI: 10.24200/amecj.v7.i01.253
S. Khodadoust, Raana Ghadri, F. Zeraatpisheh
In the present work, a copper nanowire loaded on activated carbon (Cu-NW-AC) was fabricated and applied as an effective adsorbent for the removal of bromophenol blue (BPB) dye from aqueous solutions and then the percentage of removal was evaluated by UV–Vis spectrophotometer. The synthesized adsorbent was characterized and identified using techniques like Transmission electron microscopy (TEM) and Brunauer–Emmett–Teller (BET). The effective parameters of the removal process were investigated and optimized by experimental design methodology (EDM) based on response surface methodology (RSM) as a powerful optimization method. EDM is a unique method for following the effects of different factors on the removal process simultaneously. Analysis of variance (ANOVA) was used based on p-values and F-tests to investigate the accuracy and reliability of the used method. The optimized parameters were obtained as BPB concentration of 15 mg L-1, ultrasonic irradiation time of 14 min, adsorbent dosage of 0.018 g and pH= 5.5 under the desirability function. To evaluate the adsorption mechanism and calculation of maximum adsorption capacity, different adsorption isotherms were studied and according to the results, the Langmuir isotherm model showed the highest compatibility due to its higher R2 (0.9905). Also, the proposed adsorbent represented good adsorption capacity (123.45 mg g-1).
在本研究中，制备了负载在活性炭上的铜纳米线（Cu-NW-AC），并将其作为一种有效的吸附剂用于去除水溶液中的溴酚蓝（BPB）染料，然后用紫外可见分光光度计评估了去除率。利用透射电子显微镜（TEM）和布鲁纳-艾美特-泰勒（BET）等技术对合成的吸附剂进行了表征和鉴定。基于响应面方法学（RSM）这一强大的优化方法，采用实验设计方法学（EDM）对去除过程的有效参数进行了研究和优化。EDM 是一种独特的方法，可同时跟踪不同因素对去除过程的影响。采用基于 p 值和 F 检验的方差分析 (ANOVA) 来研究所用方法的准确性和可靠性。在理想函数下，得到的优化参数为：BPB 浓度为 15 mg L-1，超声波辐照时间为 14 分钟，吸附剂用量为 0.018 g，pH= 5.5。为了评估吸附机理和计算最大吸附容量，研究了不同的吸附等温线，结果表明，Langmuir 等温线模型因其较高的 R2（0.9905）而显示出最高的兼容性。此外，所提议的吸附剂具有良好的吸附容量（123.45 毫克/克-1）。
{"title":"Analysis, construction, characterization, and application of copper nanowires loaded on activated carbon for removal of bromophenol blue in water samples","authors":"S. Khodadoust, Raana Ghadri, F. Zeraatpisheh","doi":"10.24200/amecj.v7.i01.253","DOIUrl":"https://doi.org/10.24200/amecj.v7.i01.253","url":null,"abstract":"In the present work, a copper nanowire loaded on activated carbon (Cu-NW-AC) was fabricated and applied as an effective adsorbent for the removal of bromophenol blue (BPB) dye from aqueous solutions and then the percentage of removal was evaluated by UV–Vis spectrophotometer. The synthesized adsorbent was characterized and identified using techniques like Transmission electron microscopy (TEM) and Brunauer–Emmett–Teller (BET). The effective parameters of the removal process were investigated and optimized by experimental design methodology (EDM) based on response surface methodology (RSM) as a powerful optimization method. EDM is a unique method for following the effects of different factors on the removal process simultaneously. Analysis of variance (ANOVA) was used based on p-values and F-tests to investigate the accuracy and reliability of the used method. The optimized parameters were obtained as BPB concentration of 15 mg L-1, ultrasonic irradiation time of 14 min, adsorbent dosage of 0.018 g and pH= 5.5 under the desirability function. To evaluate the adsorption mechanism and calculation of maximum adsorption capacity, different adsorption isotherms were studied and according to the results, the Langmuir isotherm model showed the highest compatibility due to its higher R2 (0.9905). Also, the proposed adsorbent represented good adsorption capacity (123.45 mg g-1). ","PeriodicalId":7797,"journal":{"name":"Analytical Methods in Environmental Chemistry Journal","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-03-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140369448","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-09-30DOI: 10.24200/amecj.v6.i03.256
Marzieh Asgari, Moloud Kazemi, Mohammad Mahmoudi Sourastani, Mona Sharififard
Using plant essential oils (EOs) as a pesticide alternative has gained increasing interest as a promising strategy to reduce the harmful effects of chemical pesticides. This study aims to investigate the chemical composition of Eucalyptus globulus Labill and Rosmarinus officinalis L. essential oils and evaluate their impacts against Blattella germanica L. under laboratory conditions. The essential oils were prepared from dried leaves using hydro-distillation (HD) as a chemical extraction method. The gas chromatography-mass spectrometry (GC-MS) was employed to analyze and identify their chemical compounds. Bioassays were conducted using the standard contact method recommended by the World Health Organization, and the data were analyzed using the probit regression model. By GC-MS analysis, the major components included 1,8-cineole (50.67%), alpha-pinene (17.48%), limonene (4.26%) for eucalyptus and alpha-pinene (20.67%), camphor (10.69%), 1,8-cineole (9.38%), Borneol (9.02%), comphene (7.15%), and limonene (4.88%) for rosemary. The LD50 values were 9. 27, 10.54, and 3.23 %, and LD95 values increased to 27.2, 22.3 %, and 14.3% for rosemary, eucalyptus, and their mixture. The EOs mixture had a higher repellent effect with a repellency rate of 98.9% at a concentration of 3% compared to 93.3% and 90% at a concentration of 5% for rosemary and eucalyptus alone.
{"title":"Chemical analysis of Eucalyptus and Rosemary essential oils using gas chromatography-mass spectrometry (GC-MS) and evaluation of their toxicity against the most common urban pest","authors":"Marzieh Asgari, Moloud Kazemi, Mohammad Mahmoudi Sourastani, Mona Sharififard","doi":"10.24200/amecj.v6.i03.256","DOIUrl":"https://doi.org/10.24200/amecj.v6.i03.256","url":null,"abstract":"Using plant essential oils (EOs) as a pesticide alternative has gained increasing interest as a promising strategy to reduce the harmful effects of chemical pesticides. This study aims to investigate the chemical composition of Eucalyptus globulus Labill and Rosmarinus officinalis L. essential oils and evaluate their impacts against Blattella germanica L. under laboratory conditions. The essential oils were prepared from dried leaves using hydro-distillation (HD) as a chemical extraction method. The gas chromatography-mass spectrometry (GC-MS) was employed to analyze and identify their chemical compounds. Bioassays were conducted using the standard contact method recommended by the World Health Organization, and the data were analyzed using the probit regression model. By GC-MS analysis, the major components included 1,8-cineole (50.67%), alpha-pinene (17.48%), limonene (4.26%) for eucalyptus and alpha-pinene (20.67%), camphor (10.69%), 1,8-cineole (9.38%), Borneol (9.02%), comphene (7.15%), and limonene (4.88%) for rosemary. The LD50 values were 9. 27, 10.54, and 3.23 %, and LD95 values increased to 27.2, 22.3 %, and 14.3% for rosemary, eucalyptus, and their mixture. The EOs mixture had a higher repellent effect with a repellency rate of 98.9% at a concentration of 3% compared to 93.3% and 90% at a concentration of 5% for rosemary and eucalyptus alone.","PeriodicalId":7797,"journal":{"name":"Analytical Methods in Environmental Chemistry Journal","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135084470","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-09-30DOI: 10.24200/amecj.v6.i03.248
Salah Bahah
The co-precipitation method synthesized the synthetic anionicMg–Al and Ni-Al clays with three molar ratios (Mg/Al, Ni/Al). The samples were characterized by powder XRD, Fourier transform infrared spectroscopy (FTIR), and scanning electron microscopy (SEM). No other crystalline phases were detected in the powder XRD patterns of the co-precipitated samples. The infrared spectra obtained all the functional groups that characterize these two types of anionic clays. SEM micrographs indicate the presence of particles and aggregates. The particles, or aggregates, are in the form of plates, supported by particles of acceptable sizes. The optimal pH for maximum lead adsorption is about 6.5 for both clays. The optimal adsorbent masses for the maximum percentages of lead removal are 0.2 g for Mg3AlCO3 and 0.25 g for Ni3AlCO3. The Mg3AlCO3 has a maximum adsorption capacity of lead, where qm=73.42 mg g-1. The adsorbed amount increases with increasing temperature for both types of clays studied. The equilibrium time of Pb2+ adsorption is reached after 5 min for both clays. The most appropriate models to describe the experimental data of adsorption kinetics and isotherms are pseudo-second-order and Langmuir. The detection limit (LOD) was 0.272 mg L-1. The linearity range was 1 to 5 mg L-1(R2 0.9997).
{"title":"Analytical study on lead elimination by anionic clays: Characterization, adsorption kinetics, isotherm, thermodynamic, mechanism and adsorption","authors":"Salah Bahah","doi":"10.24200/amecj.v6.i03.248","DOIUrl":"https://doi.org/10.24200/amecj.v6.i03.248","url":null,"abstract":"The co-precipitation method synthesized the synthetic anionicMg–Al and Ni-Al clays with three molar ratios (Mg/Al, Ni/Al). The samples were characterized by powder XRD, Fourier transform infrared spectroscopy (FTIR), and scanning electron microscopy (SEM). No other crystalline phases were detected in the powder XRD patterns of the co-precipitated samples. The infrared spectra obtained all the functional groups that characterize these two types of anionic clays. SEM micrographs indicate the presence of particles and aggregates. The particles, or aggregates, are in the form of plates, supported by particles of acceptable sizes. The optimal pH for maximum lead adsorption is about 6.5 for both clays. The optimal adsorbent masses for the maximum percentages of lead removal are 0.2 g for Mg3AlCO3 and 0.25 g for Ni3AlCO3. The Mg3AlCO3 has a maximum adsorption capacity of lead, where qm=73.42 mg g-1. The adsorbed amount increases with increasing temperature for both types of clays studied. The equilibrium time of Pb2+ adsorption is reached after 5 min for both clays. The most appropriate models to describe the experimental data of adsorption kinetics and isotherms are pseudo-second-order and Langmuir. The detection limit (LOD) was 0.272 mg L-1. The linearity range was 1 to 5 mg L-1(R2 0.9997).","PeriodicalId":7797,"journal":{"name":"Analytical Methods in Environmental Chemistry Journal","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135084743","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-09-29DOI: 10.24200/amecj.v6.i03.250
Negar Motakef Kazemi, Nooshin Nassaj
Today, polymer nanocomposites (NCs) have become important as suitable candidates for nano absorbents due to their simplicity and cheapness. This research investigated a nano absorbent based on starch nanocomposite containing hydroxyapatite (HA) and eggshell inspired by nature to absorb methylene blue (MB) as a toxic cationic dye from aqueous solution. The effect of temperature, pH, and the ratio of hydroxyapatite and eggshell absorbent on the amount of absorption after immersion in an aqueous medium was measured. The samples were identified by the UV-Vis spectrophotometer, scanning electron microscope (SEM), X-ray energy dispersive spectrometry (EDS), Fourier transform infrared (FTIR), X-ray diffraction (XRD), and BET analysis. Based on the results, the biological nanocomposite of starch-containing 0.125 g hydroxyapatite and eggshell, inspired by nature, has the highest absorption (88%) of methylene blue dye from the aqueous solution quickly. Increasing temperature, increasing pH, and decreasing the amount of nano absorbent increased the absorption of methylene blue dye from the aqueous solution. The results show that starch nanocomposite containing hydroxyapatite and eggshell can absorb methylene blue dye and have good potential for various applications, especially in medical and industrial fields.
{"title":"Starch nanocomposite containing hydroxyapatite and eggshell for absorbing methylene blue dye from aqueous solution","authors":"Negar Motakef Kazemi, Nooshin Nassaj","doi":"10.24200/amecj.v6.i03.250","DOIUrl":"https://doi.org/10.24200/amecj.v6.i03.250","url":null,"abstract":"Today, polymer nanocomposites (NCs) have become important as suitable candidates for nano absorbents due to their simplicity and cheapness. This research investigated a nano absorbent based on starch nanocomposite containing hydroxyapatite (HA) and eggshell inspired by nature to absorb methylene blue (MB) as a toxic cationic dye from aqueous solution. The effect of temperature, pH, and the ratio of hydroxyapatite and eggshell absorbent on the amount of absorption after immersion in an aqueous medium was measured. The samples were identified by the UV-Vis spectrophotometer, scanning electron microscope (SEM), X-ray energy dispersive spectrometry (EDS), Fourier transform infrared (FTIR), X-ray diffraction (XRD), and BET analysis. Based on the results, the biological nanocomposite of starch-containing 0.125 g hydroxyapatite and eggshell, inspired by nature, has the highest absorption (88%) of methylene blue dye from the aqueous solution quickly. Increasing temperature, increasing pH, and decreasing the amount of nano absorbent increased the absorption of methylene blue dye from the aqueous solution. The results show that starch nanocomposite containing hydroxyapatite and eggshell can absorb methylene blue dye and have good potential for various applications, especially in medical and industrial fields.","PeriodicalId":7797,"journal":{"name":"Analytical Methods in Environmental Chemistry Journal","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-09-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135297204","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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