电场及表面活性物质(SAS)溶液对水驱采收率影响的研究

R.G. Allakhverdiyeva
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摘要

本文研究了电流场和不同类型表面活性物质溶液对重粘土多孔介质中界面张力、吸附解吸和采收率的影响。采用非离子型醛醇、阳离子型DMABACH(二甲基烷基苄基氯化铵)和阴离子型磺酸作为SAS。Balakhany油田Kirmakian Suite (KS)地表暴露的石英砂和岩石是一种吸附剂。结果表明,50 V和100 V的直流和交流电流通过不同类型的SAS溶液对其在非极性烃液边界上的界面张力没有实际影响。直流电和交流电通过含粘土和碳酸盐的多孔介质不影响非离子SAS的动态吸附值,但促进其从岩石表面的脱附减少。结果表明,与矿化水相比,直流电场和非离子型表面活性物质的共同使用并不会对采收率产生实际影响,因为非离子型表面活性物质的分子在基尔马基组重粘土质岩石表面具有较高的吸附率。使用100 V直流电(高达23%)可以通过地层碱性水提高Kirmakian油田的采收率
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Investigation of influence of electrical field and solution of the surface-active substance (SAS) on water flood oil recovery factor
Influence of the electrical current fields and various type solutions of the surface-active substances on an interfacial tension, adsorption, desorption and on oil recovery factor from heavily clay porous medium has been investigated in the article. Nonionic alfenol, cation-active DMABACH (Dimethyl Alkyl Benzyl Ammonium Chloride) and anion-active sulfonic acid have been used as SAS. Quartz sand and rock from surface exposure of Kirmakian Suite (KS) of Balakhany field are as an adsorbent. It was revealed that direct and alternating current at 50 and 100 V through solutions of different type of SAS doesn’t practically influence on their interfacial tension on the boundary of nonpolar hydrocarbon liquid. Direct and alternating current through the porous medium containing clays and carbonates doesn’t influence on value of dynamic adsorption of nonionic SAS but promotes a decrease of their desorption from the rocks surface. It was determined that shared use of the direct-current field and solution of nonionic surface-active substance in comparison with mineralized water doesn’t practically influence on value of the oil recovery factor due to high adsorption of its molecules on surface of the heavily clay rock of Kirmakian suite. The use of direct current at 100 V considerably allowed (up to 23 %) to increase the Kirmakian oil recovery factor by the stratal alkaline water
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