{"title":"二氯四(硫脲)镍(II)的磁各向异性和极化电子能谱","authors":"M. Gerloch, J. Lewis, W. R. Smail","doi":"10.1039/J19710002434","DOIUrl":null,"url":null,"abstract":"The magnetic anistropies and powder susceptibilities of Ni(thiourea)4Cl2 are reported in the temperature range 80–300 K, together with single-crystal polarized electronic spectra at room- and liquid-helium-temperatures. The results are interpreted within a C4v crystal-field model including spin–orbit coupling.Estimates of the crystal-field radial parameters Dq, Dt, and Ds are made by fitting the magnetic and spectral results, as are values for the spin–orbit coupling and orbital reduction factors.","PeriodicalId":17321,"journal":{"name":"Journal of The Chemical Society A: Inorganic, Physical, Theoretical","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"5","resultStr":"{\"title\":\"Magnetic anisotropy and polarized electronic spectrum of dichlorotetrakis(thiourea)nickel(II)\",\"authors\":\"M. Gerloch, J. Lewis, W. R. Smail\",\"doi\":\"10.1039/J19710002434\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The magnetic anistropies and powder susceptibilities of Ni(thiourea)4Cl2 are reported in the temperature range 80–300 K, together with single-crystal polarized electronic spectra at room- and liquid-helium-temperatures. The results are interpreted within a C4v crystal-field model including spin–orbit coupling.Estimates of the crystal-field radial parameters Dq, Dt, and Ds are made by fitting the magnetic and spectral results, as are values for the spin–orbit coupling and orbital reduction factors.\",\"PeriodicalId\":17321,\"journal\":{\"name\":\"Journal of The Chemical Society A: Inorganic, Physical, Theoretical\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1971-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"5\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Chemical Society A: Inorganic, Physical, Theoretical\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/J19710002434\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society A: Inorganic, Physical, Theoretical","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/J19710002434","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Magnetic anisotropy and polarized electronic spectrum of dichlorotetrakis(thiourea)nickel(II)
The magnetic anistropies and powder susceptibilities of Ni(thiourea)4Cl2 are reported in the temperature range 80–300 K, together with single-crystal polarized electronic spectra at room- and liquid-helium-temperatures. The results are interpreted within a C4v crystal-field model including spin–orbit coupling.Estimates of the crystal-field radial parameters Dq, Dt, and Ds are made by fitting the magnetic and spectral results, as are values for the spin–orbit coupling and orbital reduction factors.